Royal Society of Chemistry

Programmable chemical reaction networks: emulating regulatory functions in living cells using a bottom-up approach

Chem. Soc. Rev. - 16 November, 2015 - 05:17

Chem. Soc. Rev., 2015, 44,7465-7483
DOI: 10.1039/C5CS00361J, Tutorial ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hendrik W. H. van Roekel, Bas J. H. M. Rosier, Lenny H. H. Meijer, Peter A. J. Hilbers, Albert J. Markvoort, Wilhelm T. S. Huck, Tom F. A. de Greef
Living cells are able to produce a wide variety of biological responses when subjected to biochemical stimuli.
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Correlation between hierarchical structure of crystal networks and macroscopic performance of mesoscopic soft materials and engineering principles

Chem. Soc. Rev. - 16 November, 2015 - 05:17

Chem. Soc. Rev., 2015, 44,7881-7915
DOI: 10.1039/C5CS00074B, Review ArticleNaibo Lin, Xiang Yang Liu
The performance of soft materials is correlated with the hierarchical crystal network structure by topology, correlation length, symmetry/ordering, and strength.
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Nanomaterial-based activatable imaging probes: from design to biological applications

Chem. Soc. Rev. - 16 November, 2015 - 05:17

Chem. Soc. Rev., 2015, 44,7855-7880
DOI: 10.1039/C4CS00476K, Review ArticleJingjing Li, Fangfang Cheng, Haiping Huang, Lingling Li, Jun-Jie Zhu
This review focuses on the design and biological applications of nanomaterial-based activatable imaging probes reported in the past five years.
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Mass spectrometry for the assessment of the occurrence and biological consequences of DNA adducts

Chem. Soc. Rev. - 16 November, 2015 - 05:17

Chem. Soc. Rev., 2015, 44,7829-7854
DOI: 10.1039/C5CS00316D, Review ArticleShuo Liu, Yinsheng Wang
In this article, we review the applications of mass spectrometry for examining the occurrence and biological consequences of DNA adducts.
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Efficient visible driven photocatalyst, silver phosphate: performance, understanding and perspective

Chem. Soc. Rev. - 16 November, 2015 - 05:17

Chem. Soc. Rev., 2015, 44,7808-7828
DOI: 10.1039/C5CS00380F, Review ArticleDavid James Martin, Guigao Liu, Savio J. A. Moniz, Yingpu Bi, Andrew M. Beale, Jinhua Ye, Junwang Tang
Photocatalysis is a promising technology that can contribute to renewable energy production from water and water purification.
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Inorganic nanoparticles engineered to attack bacteria

Chem. Soc. Rev. - 16 November, 2015 - 05:17

Chem. Soc. Rev., 2015, 44,7787-7807
DOI: 10.1039/C5CS00041F, Review ArticleKristen P. Miller, Lei Wang, Brian C. Benicewicz, Alan W. Decho
Antibiotics delivered to bacteria using engineered nanoparticles (NP), offer a powerful and efficient means to kill or control bacteria, especially those already resistant to antibiotics.
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Crucial aspects in the design of chirally modified noble metal catalysts for asymmetric hydrogenation of activated ketones

Chem. Soc. Rev. - 16 November, 2015 - 05:17

Chem. Soc. Rev., 2015, 44,7449-7464
DOI: 10.1039/C4CS00462K, Tutorial ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Alfons Baiker
This tutorial review analyzes the crucial aspects, which have to be considered in the development of heterogeneous catalytic systems based on chirally modified noble metals for asymmetric hydrogenation of activated ketones.
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Transition metal-catalyzed ketone-directed or mediated C-H functionalization

Chem. Soc. Rev. - 16 November, 2015 - 05:17

Chem. Soc. Rev., 2015, 44,7764-7786
DOI: 10.1039/C5CS00272A, Review ArticleZhongxing Huang, Hee Nam Lim, Fanyang Mo, Michael C. Young, Guangbin Dong
This review summarizes transition metal-catalyzed C-H functionalization using ketones as directing groups or substrates.
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Core-structure-inspired asymmetric addition reactions: enantioselective synthesis of dihydrobenzoxazinone- and dihydroquinazolinone-based anti-HIV agents

Chem. Soc. Rev. - 16 November, 2015 - 05:17

Chem. Soc. Rev., 2015, 44,7439-7448
DOI: 10.1039/C5CS00342C, Tutorial ReviewShen Li, Jun-An Ma
An overview of the asymmetric synthesis of dihydrobenzoxazinone- and dihydroquinazolinone-based anti-HIV agents (Efavirenz, DPC 961, DPC 963, DPC 083) and analogues was presented.
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Pharmaceuticals that contain polycyclic hydrocarbon scaffolds

Chem. Soc. Rev. - 16 November, 2015 - 05:17

Chem. Soc. Rev., 2015, 44,7737-7763
DOI: 10.1039/C4CS00477A, Review ArticleTegan P. Stockdale, Craig M. Williams
This review comprehensively explores approved pharmaceutical compounds that contain polycyclic scaffolds and the properties that these skeletons convey.
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Electronic transport properties of transition metal dichalcogenide field-effect devices: surface and interface effects

Chem. Soc. Rev. - 16 November, 2015 - 05:17

Chem. Soc. Rev., 2015, 44,7715-7736
DOI: 10.1039/C5CS00275C, Review ArticleHennrik Schmidt, Francesco Giustiniano, Goki Eda
We review the state-of-the-art electronic properties of atomically thin TMD FETs with a focus on surface and interface effects.
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A review of electrolyte materials and compositions for electrochemical supercapacitors

Chem. Soc. Rev. - 16 November, 2015 - 05:17

Chem. Soc. Rev., 2015, 44,7484-7539
DOI: 10.1039/C5CS00303B, Review ArticleCheng Zhong, Yida Deng, Wenbin Hu, Jinli Qiao, Lei Zhang, Jiujun Zhang
Electrolytes have been identified as some of the most influential components in the performance of electrochemical supercapacitors (ESs), which include: electrical double-layer capacitors, pseudocapacitors and hybrid supercapacitors. This paper reviews recent progress in the research and development of ES electrolytes.
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An S = 12 Semiquinoid Radical-Bridged Mn6 Wheel Complex Assembled from an Asymmetric Redox-Active Bridging Ligand

Chem. Commun. - 15 November, 2015 - 12:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC08482B, CommunicationIe-Rang Jeon, T David Harris
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Combining cycloisomerization with trienamine catalysis: a regiochemically flexible enantio- and diastereoselective synthesis of hexahydroindoles

Chem. Commun. - 15 November, 2015 - 12:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC08886K, CommunicationV. Chintalapudi, E. A. Galvin, R. L. Greenaway, E. A. Anderson
The synthesis of polysubstituted hexahydroindoles through trienamine-organocatalyzed cycloadditions of pyrrolidinyl dienals, prepared by palladium-catalyzed cycloisomerization, is reported.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Cooperative Reaction Chemistry Derived from a Borata-diene Framework

Chem. Commun. - 15 November, 2015 - 12:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC07954C, CommunicationGerald Kehr, G Erker, Constantin Gabriel Daniliuc, Jiangang Yu
The bifunctional frustrated BH-/B hydridoborate nucleophile/borane Lewis acid pair 6 is prepared starting from the borata-diene 3 by a sequence of sequential protonation/hydride attachment, followed by hydroboration with Piers' borane...
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In situ monitoring of catalytic process variations in a single nanowire by dark-field-assisted surface-enhanced Raman spectroscopy

Chem. Commun. - 15 November, 2015 - 12:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC09220E, CommunicationXin Shi, Haowen Li, Yi-Lun Ying, Chang Liu, Li Zhang, Yi-Tao Long
In this communication, we provide a new method for characterizing the kinetics of a catalytic process on multiple sites of a single nanowire by dark-field-assisted surface-enhanced Raman spectroscopy (DFSERS). The...
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3D Networked Polydiacetylene Sensor for Enhanced Sensitivity

Chem. Commun. - 15 November, 2015 - 12:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC08566G, CommunicationSoobum Lee, Joosub Lee, Dong Wook Lee, Jong-Man Kim, Haiwon Lee
Owing to a unique 'turn-on' fluorescence feature upon environmental stimulation, polydiacetylene (PDAs) have been actively employed in label-free sensor chips. In general, the PDA sensor chips are prepared by immobilization...
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Naphthalimide-based fluorescent probe for selectively and specifically detecting glutathione in lysosome of living cells

Chem. Commun. - 15 November, 2015 - 12:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC08328A, CommunicationJun Yin, Meijiao Cao, Haiyan Chen, Dan Chen, Zhiqiang Xu, Shenghua Liu, Xiaoqiang Chen
A novel naphthalimide-based fluorescent probe by employing a sulfonamide unit as a thiol-responsive group was reported. It is capable of efficiently distinguishing GSH from cysteine and homocysteine. Bioimaging shows that...
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Hydrazide functionalized monodispersed silica microsphere: a novel probe with tunable selectivity for versatile enrichment of phosphopeptides with different numbers of phosphorylation sites in MS analysis

Chem. Commun. - 15 November, 2015 - 12:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC07941A, CommunicationLinnan Xu, Wen Ma, Sensen Shen, Liping Li, Yu Bai, Huwei Liu
Hydrazide functionalized monodispersed silica microsphere (HFMSM) was developed for the enrichment of phosphopeptides for the first time. With the aid of the tunable selectivity of HFMSM, global enrichment or fractionation...
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Distinction between coordination and phosphine ligand oxidation: interactions of di- and triphosphines with Pn3+ (Pn = P, As, Sb, Bi)

Chem. Commun. - 15 November, 2015 - 12:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC08086J, CommunicationSaurabh Chitnis, Kevin Vos, Neil Burford, Robert McDonald, Michael J Ferguson
Reactions of polydentate phosphines with sources of Pn3+ (Pn = P, As, Sb, Bi) yield complexes of Pn1+ (Pn = P, As) or Pn3+ (Pn = Sb, Bi) acceptors. The...
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