Royal Society of Chemistry

Application of a diffusion-desorption rate equation model in astrochemistry

Faraday Disc. - 3 September, 2014 - 18:17
Faraday Discuss., 2014, 168,517-532
DOI: 10.1039/C3FD00113J, PaperJiao He, Gianfranco Vidali
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Structure of catalyst particles from in-situ electron microscopy: a web themed issue

Chem. Commun. - 3 September, 2014 - 01:54

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC90211D, EditorialFranklin (Feng) Tao, Eric A. Stach, Nigel D. Browning
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19 F magnetic resonance probes for live-cell detection of peroxynitrite using an oxidative decarbonylation reaction

Chem. Commun. - 3 September, 2014 - 01:54

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC04292A, CommunicationKevin J. Bruemmer, Sara Merrikhihaghi, Christina T. Lollar, Siti Nur Sarah Morris, Johannes H. Bauer, Alexander R. Lippert
We have developed 19F NMR probes for non-invasive monitoring of ONOO- produced by A549 cells using novel oxidative decarbonylation chemistry.
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Electrocatalytic O2 reduction by a monolayer of hemin: the role of pKa of distal and proximal oxygen of a FeIII-OOH species in determining reactivity

Chem. Commun. - 3 September, 2014 - 01:54

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC03886J, CommunicationSohini Mukherjee, Sabyasachi Bandyopadhyay, Sudipta Chatterjee, Abhishek Dey
Investigation of the proton coupled electron transfer steps involved in electrocatalytic ORR by hemin modified electrodes allows the determination of pKas of the proximal and distal oxygen atoms of a rate determining FeIII-OOH species.
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A click chemistry strategy for visualization of plant cell wall lignification

Chem. Commun. - 3 September, 2014 - 01:54

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC04692G, CommunicationYuki Tobimatsu, Dorien Van de Wouwer, Eric Allen, Robert Kumpf, Bartel Vanholme, Wout Boerjan, John Ralph
Monolignol mimics bearing chemical reporter tags and bioorthogonal click chemistry were commissioned to visualize plant cell wall lignins in vivo.
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Modification of fulleropyrazolines modulates their cleavage by light

Chem. Commun. - 3 September, 2014 - 01:54

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC03859B, CommunicationReida N. Rutte, Thomas B. Parsons, Benjamin G. Davis
The tuned photocleavage of fulleropyrazolines unveils potential for controlled release of biologically-relevant molecules or payloads.
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Adamantane-based amphiphiles (ADAs) for membrane protein study: importance of a detergent hydrophobic group in membrane protein solubilisation

Chem. Commun. - 3 September, 2014 - 01:54

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC05746E, CommunicationPil Seok Chae, Hyoung Eun Bae, Manabendra Das
Adamantane-bearing agents showed enhanced efficiency in membrane protein solubilisation, indicating the favorable role of this ring in detergent behaviors.
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A highly efficient thiazolylidene catalyzed acetoin formation: reaction, tolerance and catalyst recycling

Chem. Commun. - 3 September, 2014 - 01:54

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC04831H, CommunicationLiuqun Gu, Ting Lu, Xiukai Li, Yugen Zhang
An efficient formation of acetoin from acetaldehyde was achieved under thiazolylidene catalysis and a new type of solid supported system.
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3D reconstruction of atomic structures from high angle annular dark field (HAADF) STEM images and its application on zeolite silicalite-1

Dalton Transactions - 2 September, 2014 - 07:54

Dalton Trans., 2014, 43,14158-14163
DOI: 10.1039/C4DT01904K, PaperTom Willhammar, Alvaro Mayoral, Xiaodong Zou
The 3D atomic structure of silicalite-1 has been reconstructed for the first time by combining three high resolution HAADF-STEM images.
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Crystal lattice effect on the quenching of the intracluster magnetic interaction in [V12B18O60H6]10- polyoxometalate

Dalton Transactions - 2 September, 2014 - 07:54

Dalton Trans., 2014, 43,14132-14141
DOI: 10.1039/C4DT01561D, PaperPatricio Hermosilla-Ibanez, Walter Canon-Mancisidor, Juan Costamagna, Andres Vega, Veronica Paredes-Garcia, Maria Teresa Garland, Eric Le Fur, Olivier Cador, Evgenia Spodine, Diego Venegas-Yazigi
Quenching effect of the intracluster antiferromagnetic coupling by alkaline ions of the crystalline packing.
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Synergetic effect of Zn substitution on the electron and phonon transport in Mg2Si0.5Sn0.5-based thermoelectric materials

Dalton Transactions - 2 September, 2014 - 07:54

Dalton Trans., 2014, 43,14072-14078
DOI: 10.1039/C4DT01734J, PaperHongli Gao, Tiejun Zhu, Xinbing Zhao, Yuan Deng
Isoelectronic Zn substitution in Mg2Si0.5Sn0.5-based thermoelectric materials improved mobility without affecting carrier concentration, leading to an enhancement of ZT.
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Redox-reversible niobium-doped strontium titanate decorated with in situ grown nickel nanocatalyst for high-temperature direct steam electrolysis

Dalton Transactions - 2 September, 2014 - 07:54

Dalton Trans., 2014, 43,14147-14157
DOI: 10.1039/C4DT01430H, PaperLiming Yang, Kui Xie, Shanshan Xu, Tingshuai Wu, Qi Zhou, Ting Xie, Yucheng Wu
Electrocatalytic Ni nanoparticles largely improve the performance of the cathode for high-temperature direct steam electrolysis.
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The chloridomolybdenum(III) cluster in [BMIm]4[AgMo10Cl35] with infinite chains of Ag+-linked [Mo10Cl35]5- wheels

Dalton Transactions - 2 September, 2014 - 07:54

Dalton Trans., 2014, 43,14109-14113
DOI: 10.1039/C4DT01100G, PaperDominic Freudenmann, Claus Feldmann
[BMIm]4[AgMo10Cl35] contains a new wheel-shaped [Mo10Cl35]5- anion with five pairs of Mo-Mo bonds and Ag+ interlinking to infinite chains.
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{RuNO}6vs. co-ligand oxidation: two non-innocent groups in one ruthenium nitrosyl complex

Dalton Transactions - 2 September, 2014 - 07:54

Dalton Trans., 2014, 43,13835-13838
DOI: 10.1039/C4DT01388C, CommunicationAshley B. McQuarters, Nicolai Lehnert
The one-electron oxidation of the {RuNO}6 complex [Ru(L)(PPh3)(NO)(Cl)]2+ (where L = 1-phenyl-1-(pyridin-2-yl)-2-(pyridin-2-ylmethylene)hydrazine) leads to the generation of a co-ligand radical. This complex therefore represents a rare example of a ruthenium complex with two different non-innocent ligands bound.
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Syntheses and structures of copper complexes of 3-(6-(1H-pyrazol-1-yl)pyridin-2-yl)pyrazol-1-ide and their excellent performance in the syntheses of nitriles and aldehydes

Dalton Transactions - 2 September, 2014 - 07:54

Dalton Trans., 2014, 43,14061-14071
DOI: 10.1039/C4DT01765J, PaperDa-Wei Tan, Jing-Bo Xie, Qi Li, Hong-Xi Li, Jun-Chi Li, Hai-Yan Li, Jian-Ping Lang
[{Cu(NO3)}([small mu ]-pzpypz)]2 could efficiently catalyze the ammoxidation of alcohol to nitrile and the aerobic oxidation of alcohol to aldehyde in H2O.
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Vanadium complexes with multidentate amine bisphenols

Dalton Transactions - 2 September, 2014 - 07:54

Dalton Trans., 2014, 43,14022-14028
DOI: 10.1039/C4DT01007H, PaperM. M. Hanninen, A. Peuronen, P. Damlin, V. Tyystjarvi, H. Kivela, A. Lehtonen
Amine bisphenols react with VO(acac)2 to yield V(IV) or V(V) complexes depending on the additional hydroxyl donor in the ligand side-arm.
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Charge transfer from cobaltammine complex cations to metal fluoride anions in molecular solids with novel photoelectronic effects (metal: zirconium, titanium)

Dalton Transactions - 2 September, 2014 - 07:54

Dalton Trans., 2014, 43,14039-14044
DOI: 10.1039/C4DT01543F, PaperYu Du, Jihong Yu, Xueming Hong, Xuejin Li, Xiaoqing Tian
A charge transfer from a cobaltammine complex to zirconium fluoride ions occurring in molecular solids [Co(en)3](Ti2F11) is responsible for the novel photoelectronic effect.
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A-site sub-stoichiometry and oxygen vacancies as the origin of the electrical properties of Sr2-yLuNb1-xTixO6-[small delta] perovskite-like materials

Dalton Transactions - 2 September, 2014 - 07:54

Dalton Trans., 2014, 43,14099-14108
DOI: 10.1039/C4DT01337A, PaperZ. Maupoey, M. T. Azcondo, J. C. Perez-Flores, C. Ritter, K. Boulahya, U. Amador, F. Garcia-Alvarado
Structural features (A-site and oxygen vacancies) determined by NPD and HREM allow the explanation of the electrical properties of the title compounds.
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A binuclear Zn(II)-Zn(II) complex from a 2-hydroxybenzohydrazide-derived Schiff base for selective detection of pyrophosphate

Dalton Transactions - 2 September, 2014 - 07:54

Dalton Trans., 2014, 43,14142-14146
DOI: 10.1039/C4DT01799D, PaperJunfeng Wang, Bin Liu, Xiumin Liu, Matthew J. Panzner, Chrys Wesdemiotis, Yi Pang
A hydroxybenzohydrazide Schiff base formed a green fluorescent binuclear Zn(II)-Zn(II) complex in ethanol, which responded to various phosphate anions.
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Biomimetic layer-by-layer deposition assisted synthesis of Cu, N co-doped TiO2 nanosheets with enhanced visible light photocatalytic performance

Dalton Transactions - 2 September, 2014 - 07:54

Dalton Trans., 2014, 43,14054-14060
DOI: 10.1039/C4DT01605J, PaperXiaobo Wang, Yong Yan, Bo Hao, Ge Chen
Cu, N co-doped TiO2 nanosheet with increased visible light photocatalytic activity was synthesized by a biomimetic layer-by-layer deposition process.
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