Royal Society of Chemistry

Investigation on spin-flip reaction of Re + CH3CN by relativistic density functional theory

Dalton Transactions - 9 June, 2014 - 10:17

Dalton Trans., 2014, 43,9508-9517
DOI: 10.1039/C4DT00193A, PaperYi Xiao, Wen-Xin Ji, Wei-Xu, Xian-Yang Chen, Shu-Guang Wang
The minimal energy reaction pathway of Re + CH3CN has been investigated. The minimal energy crossing point is determined with the help of DFT fractional occupation-number (FON) approach.
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A spin-crossover complex based on a 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) ligand functionalized with a carboxylate group

Dalton Transactions - 9 June, 2014 - 10:17

Dalton Trans., 2014, 43,9406-9409
DOI: 10.1039/C4DT00327F, CommunicationAlexandre Abherve, Miguel Clemente-Leon, Eugenio Coronado, Carlos J. Gomez-Garcia, Maurici Lopez-Jorda
[Fe(bppCOOH)2](ClO4)2 shows an abrupt spin transition (T1/2 = 380 K, TLIESST = 60 K) due to a hydrogen-bonded linear network of complexes.
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The V-shaped polar molecules encapsulated into Cs (10528)-C72: stability and nonlinear optical response

Dalton Transactions - 9 June, 2014 - 10:17

Dalton Trans., 2014, 43,9655-9660
DOI: 10.1039/C3DT53329H, PaperLi-Jie Wang, Rong-Lin Zhong, Shi-Ling Sun, Hong-Liang Xu, Xiu-Mei Pan, Zhong-Min Su
The structures, stability and nonlinear optical properties of the encapsulated fullerenes M2N@C72 (M = Sc or Y, N = S or O) and the pristine cage Cs-C72 (10528) were investigated.
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Synthesis, structure and reactivity of [o-(2,6-diisopropylphenyliminomethinyl)phenyl]selenenyl selenocyanate (RSeSeCN) and related derivatives

Dalton Transactions - 9 June, 2014 - 10:17

Dalton Trans., 2014, 43,9431-9437
DOI: 10.1039/C4DT00157E, PaperPrakul Rakesh, Harkesh B. Singh, Jerry P. Jasinski, James A. Golen
The synthesis, structure and reactivity of stable selenenyl selenocyanates having a strong Se-Se bond are reported.
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Engineering plasmonic metal colloids through composition and structural design

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3823-3834
DOI: 10.1039/C3CS60347D, Tutorial ReviewN. E. Motl, A. F. Smith, C. J. DeSantis, S. E. Skrabalak
This Tutorial Review examines the effects of composition, particle size and shape, overall architecture, and local environment on the optical properties of metal colloids.
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Plasmonic nanomaterials for biodiagnostics

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3835-3853
DOI: 10.1039/C3CS60346F, Tutorial ReviewPhilip D. Howes, Subinoy Rana, Molly M. Stevens
We discuss plasmonic nanomaterials as biodiagnostic tools, and how their properties yield tunable optical signals and surface enhanced Raman signals.
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Nanoplasmonics

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3820-3822
DOI: 10.1039/C4CS90026J, EditorialLuis M. Liz-Marzan, Catherine J. Murphy, Jianfang Wang
Guest editors Luis Liz-Marzan, Catherine Murphy and Jianfang Wang introduce the Nanoplasmonics themed issue of Chemical Society Reviews.
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Optical absorption and scattering spectroscopies of single nano-objects

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3921-3956
DOI: 10.1039/C3CS60367A, Review ArticleAurelien Crut, Paolo Maioli, Natalia Del Fatti, Fabrice Vallee
This review focuses on optical detection and spectroscopy of single nano-objects for nanophysics investigation.
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Mapping plasmons at the nanometer scale in an electron microscope

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3865-3883
DOI: 10.1039/C3CS60478K, Tutorial ReviewMathieu Kociak, Odile Stephan
EELS and cathodoluminescence are highly relevant tools to map plasmons within metallic nanoparticles much smaller than the wavelength of light.
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Self-assembled plasmonic nanostructures

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3976-3991
DOI: 10.1039/C3CS60341E, Review ArticleAnna Klinkova, Rachelle M. Choueiri, Eugenia Kumacheva
This review highlights recent advances in the field of self-assembled plasmonic nanostructures, their optical properties and applications.
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Heavily-doped colloidal semiconductor and metal oxide nanocrystals: an emerging new class of plasmonic nanomaterials

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3908-3920
DOI: 10.1039/C3CS60417A, Tutorial ReviewXin Liu, Mark T. Swihart
A new class of plasmonic nanomaterials, based upon heavily-doped semiconductors and metal oxides, is rapidly developing and showing great promise for biomedical and optoelectronic applications.
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Nanoplasmonics for chemistry

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3898-3907
DOI: 10.1039/C3CS60364D, Tutorial ReviewGuillaume Baffou, Romain Quidant
We discuss how nanoplasmonics can benefit chemistry and review the most recent developments in this new and fast growing field of research.
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New materials for tunable plasmonic colloidal nanocrystals

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3957-3975
DOI: 10.1039/C3CS60265F, Review ArticleAlberto Comin, Liberato Manna
We present a review on the emerging materials for novel plasmonic colloidal nanocrystals.
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Probing subdiffraction limit separations with plasmon coupling microscopy: concepts and applications

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3884-3897
DOI: 10.1039/C3CS60340G, Tutorial ReviewLinxi Wu, Bjorn M. Reinhard
This Tutorial Review introduces the concept of distance dependent plasmon coupling and its application in biosensing and imaging.
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Super-resolution imaging of SERS hot spots

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3854-3864
DOI: 10.1039/C3CS60334B, Tutorial ReviewKatherine A. Willets
Super-resolution imaging defeats the diffraction-limit of light, allowing the spatial origin and intensity of SERS signals to be determined with <5 nm resolution.
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FD173: Spectroscopic and atomic force studies of the functionalisation of carbon surfaces: new insights into the role of the surface topography and specific chemical states.

Faraday Disc. - 8 June, 2014 - 21:54
Faraday Discuss., 2014, Accepted Manuscript
DOI: 10.1039/C4FD00061G, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Philip Rosser Davies, Carlo Buono, Robert John Davies, Thomas Jones, Jiri Kulhavy, David Morgan, Ryan Lewis, Neil J O Robinson, David J Willock
The utility of carbon materials in applications as diverse as drug delivery and photocatalysis is often undermined by the complexity of their surface chemistry; different sources of carbon giving rise...
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Biaxial aromatics with face-on/edge-on stacking adaptability: an STM/STS study of 1D nanowires assembled via rotatable ethynyls

Chem. Commun. - 8 June, 2014 - 04:17

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC02704C, CommunicationShern-Long Lee, Hung-Jen Wu, Yu-Ju Hsu, Hsiu-Hui Chen, Hsiu-Fu Hsu, Chun-hsien Chen
Biaxial aromatics with face-on/edge-on stacking adaptability.
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Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis

Chem. Commun. - 8 June, 2014 - 04:17

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC02319F, CommunicationAhmed F. Abdel-Magied, Amrendra K. Singh, Matti Haukka, Michael G. Richmond, Ebbe Nordlander
Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [([small mu ]-H)2Ru3([small mu ]3-S)(CO)7([small mu ]-P-P*)] (P-P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters.
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Porous molecular networks formed by the self-assembly of positively-charged trigonal building blocks at the liquid/solid interfaces

Chem. Commun. - 8 June, 2014 - 04:17

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC01576B, CommunicationKazukuni Tahara, Maria L. Abraham, Kosuke Igawa, Keisuke Katayama, Iris M. Oppel, Yoshito Tobe
Tris-(2-hydroxybenzylidene)triaminoguanidinium salts having six alkyl chains with proper spacing served as new molecular building blocks for the formation of porous honeycomb networks by van der Waals interaction between interdigitated alkyl chains at the liquid/graphite interfaces.
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Three-dimensional characterization of electrodeposited lithium microstructures using synchrotron X-ray phase contrast imaging

Chem. Commun. - 8 June, 2014 - 04:17

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC03187C, CommunicationDavid S. Eastwood, Paul M. Bayley, Hee Jung Chang, Oluwadamilola O. Taiwo, Joan Vila-Comamala, Daniel J. L. Brett, Christoph Rau, Philip J. Withers, Paul R. Shearing, Clare P. Grey, Peter D. Lee
The morphology of electrodeposited high surface area lithium microstructures was imaged in 3D using synchrotron X-ray phase contrast tomography.
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