Royal Society of Chemistry

Towards understanding the design of dual-modal MR/fluorescent probes to sense zinc Ions

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02981J, PaperCharlotte Rivas, Graeme J Stasiuk, Myra Sae-Heng, Nicholas J Long
A series of gadolinium complexes were synthesised in order to test the design of dual-modal probes that display a change in fluorescence or relaxivity response upon binding of zinc. A...
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Redox-active and DNA-binding coordination complexes of clotrimazole

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02883J, PaperNorah Barba Behrens, Soledad Betanzos-Lara, Nikola Paul Chmel, Matthew T. Zimmerman, Lidia R. Barron-Sosa, Claudio Garino, Luca Salassa, Alison Rodger, Julia L. Brumaghim, Isabel Gracia
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Structural variations in metal complexes of a tertiary [small alpha]-hydroxyoxime

Dalton Transactions - 22 December, 2014 - 12:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03393K, PaperDaniel D'Alessio, Daniel M. Lombardo, Jamila G. Vaughan, Brian W. Skelton, Keith R. Barnard, Mark. I. Ogden
A ligand based on commercial solvent extractant is found to support mono-, di-, and tri-nuclear coordination complexes.
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An Unprecedented 3D POM-MOF based on (7, 8)-Connected Twin Wells-Dawson Clusters: Synthesis, Structure, Electrocatalytic and Photocatalytic Properties

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03625E, CommunicationShaobin Li, Li Zhang, Kevin P. O'Halloran, Huiyuan Ma, Haijun Pang
The first (7, 8)-connected polyoxometalate-based metal-organic framework (POM-MOF) has been constructed by seven- and eight-connected twin Wells-Dawson clusters, representing the highest connection number of polyoxometalates to any mixed-connected POM-MOF to...
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Carbon Monoxide Release Properties and Molecular Structures of Thiophenolatomanganese(I) Carbonyl Complexes of the Type [(OC)4Mn([small micro]-S-Aryl)]2 (Mn-based CORMs)

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03567D, PaperMatthias Westerhausen, Ralf Mede, Helmar Gorls, Moritz Klein, Michael Schmitt, J Popp, Vaneza Paola Lorett-Velasquez, Guido Gessner, Stefan H Heinemann
Several phenylthiolatomanganese carbonyl complexes of the type [(OC)4Mn([small micro]-SR)]2 (R = Ph (1a), C6H4-4-CH3 (1b), C6H4-4-CF3 (1c), C6H4-4-F (1d), C6H4-4-Cl (1e), C6H4-4-OMe (1f), C6F5 (1g), and CH2C6H4-4-Cl (1h)) have been prepared...
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Thermoelectric efficiency of (1 x)(GeTe) x(Bi2Se0.2Te2.8) and implementation into highly performing thermoelectric power generators

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03425B, PaperJan Daniel Konig, Markus Winkler, Torben Dankwort, Anna Lena Hansen, Hans Fridtjof Pernau, Viola Duppel, Martin Jaegle, Kilian Bartholome, Lorenz Kienle, Wolfgang Bensch
Here we report for the first time on a complete simulation assisted "material to module" development of a high performance thermoelectric generator (TEG) based on the combination of a phase...
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Binary Lanthanide(III)/Nitrate and Ternary Lanthanide(III)/Nitrate/Chloride Complexes in an Ionic Liquid Containing Water: Optical Absorption and Luminescence Studies

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03479A, PaperSeraj Ansari, Lisheng Liu, Linfeng Rao
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Assembly of Silver Alkynyl Compounds with Various Nuclearities

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03394A, PaperYu-Mei Lin, Zong-Jie Guan, Kuan-Guan Liu, Zhanguo Jiang, Quan-Ming Wang
A convenient method for the synthesis of silver alkynyl compounds containing different nuclearities has been developed. The reaction of AgC[identical with]CBut and AgX (X = CF3CO2-, C2F5CO2-) in the presence of...
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Sonochemical synthesis of Au nanowires in III-I oxidation state bridged by 4,4[prime or minute]-dicyanamidobiphenyl and application as selective CO gas sensor

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03427A, PaperLeila Tabrizi, Hossein Chiniforoshan
In this research, Au nanowires, gold-containing polymers of the formula [(Au(I)-NCN-R-NCN-Au(III)-NCN-R-NCN-)]n; R: Biphenyl (or NCN-R-NCN: 4,4[prime or minute]-dicyanamidobiphenyl (bpH2)), have been synthesized by sonochemical process. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS),...
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Tuneable Dynamics of a Scandium Nitride Cluster Inside an Ih-C80 Cage

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02892A, CommunicationYongqiang Feng, Taishan Wang, Junfeng Xiang, Li-Hua Gan, bo wu, Li Jiang, Chun-Ru Wang
The internal clusters in metallofullerenes usually exhibit certain motion that is potentially usable in molecular gyroscopes and nano-machines. Based on 45Sc NMR, the motion of the scandium nitride cluster within...
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The synthesis of ZnO/SnO2 porous nanofibers for dye adsorption and degradation

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03382E, PaperXiang Chen, Feng Zhang, Qian Wang, Xiao Han, Xin Li, Jiuyu Liu, Huiming Lin, Fengyu Qu
ZnO/SnO2 hetero-nanofibers about 250 nm in diameter and several micrometers in length are synthesized via electrospun method by using zinc chloride and stannous chloride as inorganic source. All fibers are...
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A strategy to enhance efficiency in dye-sensitized solar cells by highly efficient TiO2/ZnS photoanode

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03102D, PaperS Srinivasa Rao, Dinah Punnoose, Ch Venkata Tulasivarma, CH.S.S Pavan Kumar, Chandu V.V.M Gopi, Soo-Kyoung Kim, Heeje Kim
In dye-sensitized solar cells (DSSCs), the TiO2 photoanode film plays an important role in increasing the power conversion efficiency. In this work, TiO2 nanoparticles were first coated on fluorine-doped tin...
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Luminescent Pt(II) Complexes Bearing Dual Isoquinolinyl Pyrazolates: Fundamentals and Applications

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03028A, PaperHsiao Yun Ku, bihai tong, Yun Chi, Hao-Che Kao, Chia-Chi Yeh, Chih-Hao Chang, Gene-Hsiang Lee
A series of four Pt(II) metal complexes with trans-arranged isoquinolinyl azolates have been prepared, [Pt(Lx)2], x = 1 ~ 4, (1 ~ 4). The associated chelates possess various substituents; namely:...
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Reductive Lithium Insertion into B-cation deficient Niobium Perovskite Oxides

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03193H, PaperAntonio Perejon, Michael Andrew Hayward
Reaction between LiH and the AnBn-1O3n cation deficient perovskite phases Ba5Nb4O15, Ba6TiNb4O18 and Ba3LaNb3O12 proceeds by reductive lithium insertion leading to the formation of Ba5LiNb4O15, Ba6LiTiNb4O18 and Ba3LaLiNb3O12 respectively. During...
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Technetium-99m and rhenium-188 complexes with one and two pendant bisphosphonate groups for imaging arterial calcification

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02965H, PaperPhilip J Blower, Jayanta Kumar Bordoloi, David Berry, Irfan Ullah Khan, Kavitha Sunassee, Rafael T. M. de Rosales, Catherine Shanahan
The first 99mTc and 188Re radiopharmaceuticals containing two pendant bisphosphonate groups has been synthesised, based on the mononuclear M(V) nitride core with two dithiocarbamate ligands each with a pendant bisphosphonate....
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Solid-phase cyclopalladation in S,C,S'-pincer systems: rising alternative to synthesis in solution

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03477E, PaperDiana V. Aleksanyan, Zinaida Klemenkova, Andrey A. Vasil'ev, Arkadii Ya. Gorenberg, Yulia V. Nelyubina, Vladimir A. Kozlov
In pursuit of a new simple approach to complex organometallic systems, a possibility of formation of the palladium-carbon bond in the solid state via direct cyclopalladation has been studied toward...
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Switchable Platinum-based Tweezers with Pt-Pt Bonding and Selective Luminescence Quenching

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03230F, PaperBernold Hasenknopf, Benjamin Doistau, Caroline Rossi-Gendron, Arnaud Tron, Nathan D McClenaghan, Lise-Marie Chamoreau, Guillaume Vives
Molecular tweezers incorporating peripheral platinum salphen complexes and a central chelating terpyridine group have been synthesized. The terpyridine can be switched upon metal binding between a free 'W' shaped form...
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Three new solvent-directed Cd(II)-based MOFs with unique luminescent properties and highly selective sensor for Cu2+ cations and nitrobenzene

Dalton Transactions - 22 December, 2014 - 12:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03415E, PaperYao-Yu Wang, Guo-Ping Yang, Yun-Long Wu
Three new solvent-induced metal-organic frameworks (MOFs), [Cd(H2L)(H2O)3][round bullet, filled]NMP (1), [Cd3(L)(H2O)4(OH)2] (2) and [Cd(L)0.5(H2O)2][round bullet, filled]H2O (3), have been rationally designed and successfully prepared via solvothermal reaction by the multidentate phenyltetracarboxylic acid [1,1':4',1''-terphenyl]-2',3,3'',5'-tetracarboxylic acid...
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A fluoride bridged {CrIII4DyIII4} single molecule magnet

Dalton Transactions - 22 December, 2014 - 12:17

Dalton Trans., 2015, 44,912-915
DOI: 10.1039/C4DT03100H, CommunicationStuart K. Langley, Craig M. Forsyth, Boujemaa Moubaraki, Keith S. Murray
Fluoride bridging between DyDy neighbours in an octanuclear {CrIII4DyIII4} cluster of the 'square-in-square' structural type is the key reason for enhanced single molecule magnetic properties of Cr-Dy SMMs and, particularly, when compared to a reported azido bridged {CrIII4DyIII4} structural analogue.
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Synthesis of aromatic functionalized cage-rearranged silsesquioxanes (T8, T10, and T12) via nucleophilic substitution reactions

Dalton Transactions - 22 December, 2014 - 12:17

Dalton Trans., 2015, 44,916-919
DOI: 10.1039/C4DT02941K, CommunicationSupansa Chimjarn, Rungthip Kunthom, Prapassorn Chancharone, Rapheepraew Sodkhomkhum, Preeyanuch Sangtrirutnugul, Vuthichai Ervithayasuporn
Organic-inorganic hybrid nano-building blocks of aryl nitro-, aldehyde-, and bromo-functionalized polyhedral oligomeric silsesquioxanes (T8, T10, and T12) were easily prepared through nucleophilic substitutions.
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