Royal Society of Chemistry

"Click" reactions: a versatile toolbox for the synthesis of peptide-conjugates

Chem. Soc. Rev. - 20 October, 2014 - 06:54

Chem. Soc. Rev., 2014, 43,7013-7039
DOI: 10.1039/C4CS00139G, Review ArticleWen Tang, Matthew L. Becker
Peptides that comprise the functional subunits of proteins have been conjugated to versatile materials (biomolecules, polymers, surfaces and nanoparticles) in an effort to modulate cell responses, specific binding affinity and/or self-assembly behavior.
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Arene C-H functionalisation using a removable/modifiable or a traceless directing group strategy

Chem. Soc. Rev. - 20 October, 2014 - 06:54

Chem. Soc. Rev., 2014, 43,6906-6919
DOI: 10.1039/C4CS00137K, Tutorial ReviewFengzhi Zhang, David R. Spring
Recent advances in arene C-H functionalisation using a removable/modifiable or a traceless directing group strategy are reviewed.
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Single-molecule toroics in Ising-type lanthanide molecular clusters

Chem. Soc. Rev. - 20 October, 2014 - 06:54

Chem. Soc. Rev., 2014, 43,6894-6905
DOI: 10.1039/C4CS00095A, Tutorial ReviewLiviu Ungur, Shuang-Yan Lin, Jinkui Tang, Liviu F. Chibotaru
Bistable molecules with a toroidal magnetic state (single-molecule toroics) are promising for applications in quantum computing and information storage.
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Structural and functional photoacoustic molecular tomography aided by emerging contrast agents

Chem. Soc. Rev. - 20 October, 2014 - 06:54

Chem. Soc. Rev., 2014, 43,7132-7170
DOI: 10.1039/C4CS00086B, Review ArticleLiming Nie, Xiaoyuan Chen
Emerging optical contrast agents substantially advance photoacoustic molecular tomography on sensitivity and specificity enhancement, structural and functional imaging.
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Recent progress in low-voltage cathodoluminescent materials: synthesis, improvement and emission properties

Chem. Soc. Rev. - 20 October, 2014 - 06:54

Chem. Soc. Rev., 2014, 43,7099-7131
DOI: 10.1039/C4CS00109E, Review ArticleGuogang Li, Jun Lin
This review is devoted to the recent progress in the synthesis and improvement of low-voltage cathodoluminescent materials for field emission displays.
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Heteroatom-doped graphene materials: syntheses, properties and applications

Chem. Soc. Rev. - 20 October, 2014 - 06:54

Chem. Soc. Rev., 2014, 43,7067-7098
DOI: 10.1039/C4CS00141A, Review ArticleXuewan Wang, Gengzhi Sun, Parimal Routh, Dong-Hwan Kim, Wei Huang, Peng Chen
Heteroatom doping endows graphene with new or improved properties and greatly enhances its potential for various applications.
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Smart chemistry in polymeric nanomedicine

Chem. Soc. Rev. - 20 October, 2014 - 06:54

Chem. Soc. Rev., 2014, 43,6982-7012
DOI: 10.1039/C4CS00133H, Review ArticleRong Tong, Li Tang, Liang Ma, Chunlai Tu, Ryan Baumgartner, Jianjun Cheng
This review provides an overview of smart chemistry developed and utilized in the last 5-10 years in polymer-based drug delivery nanomedicine.
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Plasmon-driven photoregeneration of cofactor molecules

Chem. Commun. - 19 October, 2014 - 13:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC07829B, CommunicationAna Sanchez-Iglesias, Andrey Chuvilin, Marek Grzelczak
Platinum-doped gold nanorods are capable to regenerate cofactor molecules under visible and infrared light irradiation. Our results suggest promising use of plasmonic particles in biochemical reactions.
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Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

Chem. Commun. - 19 October, 2014 - 13:17

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC05727A, CommunicationMonica C. So, M. Hassan Beyzavi, Rohan Sawhney, Osama Shekhah, Mohamed Eddaoudi, Salih S. Al-Juaid, Joseph T. Hupp, Omar K. Farha
Solvent-assisted linker exchange and post-assembly linker metalation converts existing metal-organic framework (MOF) thin films into new or modified ones.
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Biomimetic Transparent and Superhydrophobic Coatings: From Nature and Beyond Nature

Chem. Commun. - 19 October, 2014 - 13:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC06868H, Feature ArticleShen Yu, Zhiguang Guo, Weimin Liu
It is well known that highly optical transparence is one of the most crucial criteria for an overwhelming majority of optical devices and correlative facilities including smart windows, camera lenses,...
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Upconversion luminescent logic gates and turn-on sensing of glutathione based on two-photon excited quantum dots conjugated with dopamine

Chem. Commun. - 19 October, 2014 - 13:17

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC06181K, CommunicationRijun Gui, Hui Jin, Xifeng Liu, Zonghua Wang, Feifei Zhang, Jianfei Xia, Min Yang, Sai Bi
This article reported the two-photon excited quantum dots-based novel upconversion luminescent logic gates for turn-on sensing of glutathione.
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Framework Stabilization of Si-Rich LTA Zeolite Prepared in Organic-Free Media

Chem. Commun. - 19 October, 2014 - 13:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC07396G, CommunicationMarlon T Conato, Matthew D Oleksiak, B. Peter McGrail, Radha Kishan Motkuri, Jeffrey D Rimer
Zeolite HOU-2 (LTA type) is prepared with the highest silica content (Si/Al = 2.1) reported for Na-LTA zeolites without the use of an organic structure-directing agent. The rational design of...
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Orthogonal Selectivity with Cinnamic Acids in 3- substituted Benzofuran Synthesis through C-H Olefination of Phenols

Chem. Commun. - 19 October, 2014 - 13:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC07026G, CommunicationSoumitra Agasti, Upendra Sharma, Togati Naveen, Debabrata Maiti
A palladium catalyzed intermolecular annulation of cinnamic acids and phenols has been achieved for the selective synthesis of 3-substituted benzofurans. Isotope labeling, competition experiments, kinetic studies, and intermediate trapping have...
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A rapid and divergent access to chiral azacyclic nucleoside analogues via highly enantioselective 1,3-dipolar cycloaddition of [small beta]-nucleobase substituted acrylates

Chem. Commun. - 19 October, 2014 - 13:17

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC06632D, CommunicationQi-Liang Yang, Ming-Sheng Xie, Chao Xia, Huan-Li Sun, Dan-Jie Zhang, Ke-Xin Huang, Zhen Guo, Gui-Rong Qu, Hai-Ming Guo
A rapid and divergent access to chiral azacyclic nucleoside analogues was developed via enantioselective 1,3-dipolar cycloaddition of [small beta]-nucleobase substituted acrylates.
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A highly efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides

Chem. Commun. - 19 October, 2014 - 13:17

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC06457G, CommunicationDengke Li, Ning Xu, Yicheng Zhang, Lei Wang
A Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides was developed. Anilides afforded ortho-arylation products, and N-methoxyarylamides gave phenanthridinones.
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Ru-catalyzed decarboxylative cyclization of mandelic acids with acrylates: facile access to the phthalide skeleton

Chem. Commun. - 19 October, 2014 - 13:17

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC06331G, CommunicationLili Chen, Hongji Li, Feng Yu, Lei Wang
A Ru-catalyzed decarboxylative cyclization of mandeic acids with acrylates was developed, which provides an efficient route to the phthalide skeleton.
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Extending the shell-isolated nanoparticle-enhanced Raman spectroscopy approach to interfacial ionic liquids at single crystal electrode surfaces

Chem. Commun. - 19 October, 2014 - 13:17

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC06269H, CommunicationMeng Zhang, Li-Juan Yu, Yi-Fan Huang, Jia-Wei Yan, Guo-Kun Liu, De-Yin Wu, Zhong-Qun Tian, Bing-Wei Mao
We employ, for the first time, SHINERS to study single crystal electrode surfaces in ionic liquids, and combine DFT calculations to elucidate the structural details of imidazolium-based ionic liquid-Au single crystal electrode interfaces.
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Redox-induced fluoride ligand dissociation stabilized by intramolecular hydrogen bonding

Chem. Commun. - 19 October, 2014 - 13:17

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC06832G, CommunicationCameron M. Moore, Nathaniel K. Szymczak
Appended hydrogen-bonding groups enable the reduction and F- capture of a tripodal copper fluoride complex.
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Direct exfoliation of carbon allotropes with structural analogues of self-assembled nanostructures and their photovoltaic applications

Chem. Commun. - 19 October, 2014 - 13:17

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC05929H, CommunicationWoochul Lee, Dong-Woo Lee, Myongsoo Lee, Jong-In Hong
The self-assembled nanostructures of amphiphilic molecules enabled a direct exfoliation of carbon allotropes, which were successfully introduced into the HTL layer.
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[small alpha]-Trifluoromethyl-(indol-3-yl)methanols as trifluoromethylated C3 1,3-dipoles: [3+2] cycloaddition for the synthesis of 1-(trifluoromethyl)-cyclopenta[b]indole alkaloids

Chem. Commun. - 19 October, 2014 - 13:17

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC05895J, CommunicationJinhuan Dong, Ling Pan, Xianxiu Xu, Qun Liu
Easily available [small alpha]-trifluoromethyl 3-indolylmethanol silyl ethers acting as the trifluoromethylated C3 1,3-dipoles in the preparation of 1-trifluoromethyl cyclopenta[b]indole alkaloids.
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