Royal Society of Chemistry

A novel Prins cascade process for the stereoselective synthesis of oxa-bicycles

Org. and Biomol. Chem. - 22 February, 2015 - 15:54

Org. Biomol. Chem., 2015, 13,2669-2672
DOI: 10.1039/C4OB02347A, PaperB. V. Subba Reddy, A. Venkateswarlu, B. Sridevi, Kanakaraju Marumudi, A. C. Kunwar, G. Gayatri
E- and Z-9-Methyldeca-3,8-dien-1-ols undergo smooth cyclization with aldehydes in the presence of 20 mol% AgSbF6 under extremely mild conditions to generate the corresponding oxa-bicycles in good yields with excellent selectivity.
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A comparison of chemiluminescent acridinium dimethylphenyl ester labels with different conjugation sites

Org. and Biomol. Chem. - 22 February, 2015 - 15:54

Org. Biomol. Chem., 2015, 13,2622-2633
DOI: 10.1039/C4OB02528H, PaperAnand Natrajan, David Wen
Chemiluminescent acridinium esters containing conjugation sites at the acridinium nitrogen show increased light yield when labeled to proteins.
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A facile and high-yield formation of dipyrrin-boronic acid dyads and triads: a light-harvesting system in the visible region based on the efficient energy transfer

Org. and Biomol. Chem. - 22 February, 2015 - 15:54

Org. Biomol. Chem., 2015, 13,2574-2581
DOI: 10.1039/C4OB02351J, PaperMasaki Yamamura, Shinya Yazaki, Motofumi Seki, Yasunori Matsui, Hiroshi Ikeda, Tatsuya Nabeshima
Artificial light-harvesting systems, Ar,O-BODIPY dyads and triads conjugated with a light harvester, were synthesized in high yield by the reaction of an N2O2-type dipyrrin with boronic acids.
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An overview of nanoparticles commonly used in fluorescent bioimaging

Chem. Soc. Rev. - 22 February, 2015 - 14:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00392F, Review ArticleOtto S. Wolfbeis
This article gives an overview of the various kinds of nanoparticles (NPs) that are widely used for purposes of fluorescent imaging, mainly of cells and tissues.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Biodegradable stimuli-responsive polypeptide materials prepared by ring opening polymerization

Chem. Soc. Rev. - 22 February, 2015 - 14:17

Chem. Soc. Rev., 2015, 44,612-622
DOI: 10.1039/C4CS00271G, Tutorial ReviewYong Shen, Xiaohui Fu, Wenxin Fu, Zhibo Li
This tutorial review summarizes the most recent progress in stimuli-responsive polypeptides over the past decade.
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Strategies for the asymmetric functionalization of indoles: an update

Chem. Soc. Rev. - 22 February, 2015 - 14:17

Chem. Soc. Rev., 2015, 44,742-778
DOI: 10.1039/C4CS00209A, Review ArticleRenato Dalpozzo
During the past four years, the research of new synthetic methodologies for the rapid construction of enantiomerically pure substituted indole has had a fruitful and important growth.
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Photoelectrochemical bioanalysis: the state of the art

Chem. Soc. Rev. - 22 February, 2015 - 14:17

Chem. Soc. Rev., 2015, 44,729-741
DOI: 10.1039/C4CS00228H, Review ArticleWei-Wei Zhao, Jing-Juan Xu, Hong-Yuan Chen
This review provides a panoramic snapshot of the state of the art in the dynamically developing field of photoelectrochemical bioanalysis.
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Nanostructured Mn-based oxides for electrochemical energy storage and conversion

Chem. Soc. Rev. - 22 February, 2015 - 14:17

Chem. Soc. Rev., 2015, 44,699-728
DOI: 10.1039/C4CS00218K, Review ArticleKai Zhang, Xiaopeng Han, Zhe Hu, Xiaolong Zhang, Zhanliang Tao, Jun Chen
This review summarizes recent efforts made to use nanostructured Mn-based oxides for primary batteries, Li secondary batteries, metal-air batteries, and pseudocapacitors.
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Gold-catalyzed cyclopropanation reactions using a carbenoid precursor toolbox

Chem. Soc. Rev. - 22 February, 2015 - 14:17

Chem. Soc. Rev., 2015, 44,677-698
DOI: 10.1039/C4CS00304G, Review ArticleDeyun Qian, Junliang Zhang
This review highlights recent advances in gold-catalyzed selective cyclopropanation divided by the type of carbenoid precursors.
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Photo-responsive pseudorotaxanes and assemblies

Chem. Soc. Rev. - 22 February, 2015 - 14:17

Chem. Soc. Rev., 2015, 44,663-676
DOI: 10.1039/C4CS00295D, Tutorial ReviewAmal Kumar Mandal, Monalisa Gangopadhyay, Amitava Das
Optical responses for understanding the dynamic conformational change(s) in solution during the stimuli responsive complexation and decomplexation process(es) in a supramolecular assembly.
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Supramolecular polymers constructed by orthogonal self-assembly based on host-guest and metal-ligand interactions

Chem. Soc. Rev. - 22 February, 2015 - 14:17

Chem. Soc. Rev., 2015, 44,815-832
DOI: 10.1039/C4CS00327F, Review ArticlePeifa Wei, Xuzhou Yan, Feihe Huang
This review describes recent progress in the orthogonal construction of supramolecular polymers based on host-guest and metal coordination interactions.
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Emergence of fiber supercapacitors

Chem. Soc. Rev. - 22 February, 2015 - 14:17

Chem. Soc. Rev., 2015, 44,647-662
DOI: 10.1039/C4CS00286E, Tutorial ReviewDingshan Yu, Qihui Qian, Li Wei, Wenchao Jiang, Kunli Goh, Jun Wei, Jie Zhang, Yuan Chen
Fiber supercapacitors utilizing one-dimensional cylindrically shaped fibers as electrodes have shown great application potential in wearable electronics and smart textiles.
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Surface chemical-modification for engineering the intrinsic physical properties of inorganic two-dimensional nanomaterials

Chem. Soc. Rev. - 22 February, 2015 - 14:17

Chem. Soc. Rev., 2015, 44,637-646
DOI: 10.1039/C4CS00302K, Tutorial ReviewYuqiao Guo, Kun Xu, Changzheng Wu, Jiyin Zhao, Yi Xie
This tutorial review summarizes the recent advances in engineering the intrinsic physical properties of inorganic two-dimensional nanomaterials by surface chemical modification.
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Electrosprayed nanoparticles and electrospun nanofibers based on natural materials: applications in tissue regeneration, drug delivery and pharmaceuticals

Chem. Soc. Rev. - 22 February, 2015 - 14:17

Chem. Soc. Rev., 2015, 44,790-814
DOI: 10.1039/C4CS00226A, Review ArticleRadhakrishnan Sridhar, Rajamani Lakshminarayanan, Kalaipriya Madhaiyan, Veluchamy Amutha Barathi, Keith Hsiu Chin Lim, Seeram Ramakrishna
The role of electrospun and electrosprayed natural polymers or drug ingredients for pharmaceutical and tissue engineering applications is presented in this review.
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Atomically-thin two-dimensional sheets for understanding active sites in catalysis

Chem. Soc. Rev. - 22 February, 2015 - 14:17

Chem. Soc. Rev., 2015, 44,623-636
DOI: 10.1039/C4CS00236A, Tutorial ReviewYongfu Sun, Shan Gao, Fengcai Lei, Yi Xie
Atomically-thin two-dimensional sheets can serve as an ideal model to disclose the role of active sites in catalysis.
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Integrative self-sorting: a versatile strategy for the construction of complex supramolecular architecture

Chem. Soc. Rev. - 22 February, 2015 - 14:17

Chem. Soc. Rev., 2015, 44,779-789
DOI: 10.1039/C4CS00305E, Review ArticleOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zhenfeng He, Wei Jiang, Christoph A. Schalley
Integrative self-sorting expands the concepts of self-assembly and allows the programming of supramolecular architecture on a higher level of complexity.
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Nickel-catalyzed thiolation of unactivated aryl C-H bonds: efficient access to diverse aryl sulfides

Chem. Commun. - 21 February, 2015 - 21:17

Chem. Commun., 2015, 51,4069-4072
DOI: 10.1039/C4CC10446C, CommunicationSheng-Yi Yan, Yue-Jin Liu, Bin Liu, Yan-Hua Liu, Bing-Feng Shi
A nickel-catalyzed thiolation of unactivated C(sp2)-H bonds with disulfides employing the PIP directing group was described. This process uses a catalytic nickel catalyst and no metallic oxidants or cocatalysts are required. Moreover, the reaction tolerates various important functional groups and heteroarenes.
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Asymmetric organocatalytic synthesis of quaternary [small alpha]-hydroxy phosphonates: en route to [small alpha]-aryl phosphaisoserines

Chem. Commun. - 21 February, 2015 - 21:17

Chem. Commun., 2015, 51,4077-4080
DOI: 10.1039/C4CC10390D, CommunicationInmaculada Serrano, David Monge, Eleuterio Alvarez, Rosario Fernandez, Jose M. Lassaletta
The dual activation of acyl phosphonates and formaldehyde tert-butyl hydrazone by a BINAM-derived bis-urea catalyst is the key to achieve high reactivities and enantioselectivities in the synthesis of densely functionalized quaternary [small alpha]-hydroxy phosphonates.
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Microwave selective effect: a new approach towards oxygen inhibition removal for highly-effective NO decomposition by microwave catalysis over BaMnxMg1-xO3 mixed oxides at low temperature under excess oxygen

Chem. Commun. - 21 February, 2015 - 21:17

Chem. Commun., 2015, 51,4073-4076
DOI: 10.1039/C4CC10288F, CommunicationWentao Xu, Jicheng Zhou, Yingpiao Ou, Yushang Luo, Zhimin You
Oxygen inhibition removal by microwave selective effect under microwave irradiation.
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Field-induced slow magnetic relaxation of octahedrally coordinated mononuclear Fe(III)-, Co(II)-, and Mn(III)-containing polyoxometalates

Chem. Commun. - 21 February, 2015 - 21:17

Chem. Commun., 2015, 51,4081-4084
DOI: 10.1039/C4CC09435B, CommunicationRinta Sato, Kosuke Suzuki, Takuo Minato, Masahiro Shinoe, Kazuya Yamaguchi, Noritaka Mizuno
Polyoxometalates with highly distorted octahedrally coordinated mononuclear Fe(III)-, Co(II)-, and Mn(III) ions have been synthesized, and they showed large magnetic anisotropy and single-molecule magnet behavior.
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