Royal Society of Chemistry

Control of reaction pathways in the photochemical reaction of a quinone with tetramethylethylene by metal binding

Org. and Biomol. Chem. - 26 August, 2014 - 18:54

Org. Biomol. Chem., 2014, 12,7004-7017
DOI: 10.1039/C4OB00659C, PaperHiroaki Yamamoto, Kei Ohkubo, Seiji Akimoto, Shunichi Fukuzumi, Akihiko Tsuda
Supramolecular photochemical reactions of a quinone derivative, bearing an oligoether sidearm, with tetramethylethylene occur upon noncovalent complexations with metal salts.
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Evaluation of 4-substituted styrenes as functional monomers for the synthesis of theophylline-specific molecularly imprinted polymers

Org. and Biomol. Chem. - 26 August, 2014 - 18:54

Org. Biomol. Chem., 2014, 12,6994-7003
DOI: 10.1039/C4OB00517A, PaperHazit Zayas, Clovia I. Holdsworth, Michael C. Bowyer, Adam McCluskey
Six novel functional monomers (M1-M6) were examined for their ability to imprint theophylline (1). The best selectivity was observed with M2.
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Core-level transient absorption spectroscopy as a probe of electron hole relaxation in photoionized H+(H2O)n

Faraday Disc. - 26 August, 2014 - 16:17
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C4FD00078A, PaperZheng Li, Mohamed El-Amine Madjet, Oriol Vendrell, Robin Santra
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Multiple ionization and fragmentation dynamics of molecular iodine studied in IR-XUV pump-probe experiments

Faraday Disc. - 26 August, 2014 - 16:17
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C4FD00031E, PaperK. Schnorr, A. Senftleben, G. Schmid, A. Rudenko, M. Kurka, K. Meyer, L. Foucar, M. Kubel, M. F. Kling, Y. H. Jiang, S. Dusterer, R. Treusch, C. D. Schroter, J. Ullrich, T. Pfeifer, R. Moshammer
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Signal to noise considerations for single crystal femtosecond time resolved crystallography of the Photoactive Yellow Protein

Faraday Disc. - 26 August, 2014 - 16:17
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C4FD00011K, PaperJasper J. van Thor, Mark M. Warren, Craig N. Lincoln, Matthieu Chollet, Henrik Till Lemke, David M. Fritz, Marius Schmidt, Jason Tenboer, Zhong Ren, Vukica Srajer, Keith Moffat, Tim Graber
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Sub-THz specific relaxation times of hydrogen bond oscillations in E.coli thioredoxin. Molecular dynamics and statistical analysis

Faraday Disc. - 26 August, 2014 - 16:17
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C4FD00029C, PaperTatiana Globus, Igor Sizov, Boris Gelmont
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A low temperature, isothermal gas-phase system for conversion of methane to methanol over Cu-ZSM-5

Chem. Commun. - 25 August, 2014 - 22:54

Chem. Commun., 2014, 50,11053-11055
DOI: 10.1039/C4CC02832E, CommunicationT. Sheppard, C. D. Hamill, A. Goguet, D. W. Rooney, J. M. Thompson
A low temperature, recyclable process for partial methane oxidation is described over Cu-ZSM-5 using NO as the oxidant.
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Luminescent materials containing multiple benzoxaphosphole units

Chem. Commun. - 25 August, 2014 - 22:54

Chem. Commun., 2014, 50,11036-11038
DOI: 10.1039/C4CC05259E, CommunicationShanshan Wu, Arnold L. Rheingold, John D. Protasiewicz
A series of bisbenzoxaphospholes and a trisbenzoxaphosphole have been prepared and characterized.
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A self-assembled ultrathin crystalline polymer film for high performance phototransistors

Chem. Commun. - 25 August, 2014 - 22:54

Chem. Commun., 2014, 50,11000-11003
DOI: 10.1039/C4CC04547E, CommunicationHui Li, Yishi Wu, Xuedong Wang, Qinghua Kong, Hongbing Fu
An ultrathin crystalline polymer film was prepared using a novel solution-phase self-assembled method and exhibited high performance in phototransistor devices.
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Cu-Catalyzed Suzuki-Miyaura reactions of primary and secondary benzyl halides with arylboronates

Chem. Commun. - 25 August, 2014 - 22:54

Chem. Commun., 2014, 50,11060-11062
DOI: 10.1039/C4CC05376A, CommunicationYan-Yan Sun, Jun Yi, Xi Lu, Zhen-Qi Zhang, Bin Xiao, Yao Fu
A copper-catalyzed coupling of arylboronates with primary and secondary benzyl halides with [small beta] hydrogens or steric hindrance is described.
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Stepwise assembly of an adamantoid Ru4Ag6 cage by control of metal coordination geometry at specific sites

Chem. Commun. - 25 August, 2014 - 22:54

Chem. Commun., 2014, 50,10979-10982
DOI: 10.1039/C4CC05421K, CommunicationAlexander J. Metherell, Michael D. Ward
A Ru(II) tris-chelate complex with three pendant binding sites on the same face combines with Ag(I) ions to form a Ru4Ag6 cage.
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Gold nanoparticles decorated by clustered multivalent cone-glycocalixarenes actively improve the targeting efficiency toward cancer cells

Chem. Commun. - 25 August, 2014 - 22:54

Chem. Commun., 2014, 50,11029-11032
DOI: 10.1039/C4CC03159H, CommunicationSvetlana Avvakumova, Paola Fezzardi, Laura Pandolfi, Miriam Colombo, Francesco Sansone, Alessandro Casnati, Davide Prosperi
A novel approach for multivalent targeting by using gold nanoparticles noncovalently decorated by tight functionalization with a cone-glycocalixarene bearing four mannose units is reported.
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Nanometer-sized manganese oxide-quenched fluorescent oligonucleotides: an effective sensing platform for probing biomolecular interactions

Chem. Commun. - 25 August, 2014 - 22:54

Chem. Commun., 2014, 50,11049-11052
DOI: 10.1039/C4CC04573D, CommunicationDinggeng He, Xiaoxiao He, Kemin Wang, Xue Yang, Xiaoxiao Yang, Xuecai Li, Zhen Zou
Nanometer-sized manganese oxide (nano-MnO2) consisting of some MnO2 platelets was established as a new class of label-free sensing platform for probing biomolecular interactions in a homogeneous solution.
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Unexpected cluster formation upon hydroboration of a neutral diborene with 9-BBN

Chem. Commun. - 25 August, 2014 - 22:54

Chem. Commun., 2014, 50,10983-10985
DOI: 10.1039/C4CC04476B, CommunicationHolger Braunschweig, Christian Horl
Attempts to hydroborate a boron-boron double bond using a dialkylborane lead unexpectedly to formation of rare triborane clusters.
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GeH: a novel material as a visible-light driven photocatalyst for hydrogen evolution

Chem. Commun. - 25 August, 2014 - 22:54

Chem. Commun., 2014, 50,11046-11048
DOI: 10.1039/C4CC03636K, CommunicationZhenhua Liu, Zaizhu Lou, Zhujie Li, Gang Wang, Zeyan Wang, Yuanyuan Liu, Baibiao Huang, Shengqing Xia, Xiaoyan Qin, Xiaoyang Zhang, Ying Dai
A novel photocatalyst (GeH), with 2D layered structure, was found for the first time to exhibit photocatalytic activity in the hydrogen evolution of water splitting and decomposition of organic contaminants under irradiation of visible light.
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Red-luminescent biphosphine stabilized 'Cu12S6' cluster molecules

Chem. Commun. - 25 August, 2014 - 22:54

Chem. Commun., 2014, 50,11043-11045
DOI: 10.1039/C4CC04702H, CommunicationXiao-Xun Yang, Ibrahim Issac, Sergej Lebedkin, Michael Kuhn, Florian Weigend, Dieter Fenske, Olaf Fuhr, Andreas Eichhofer
The copper sulfide cluster [Cu12S6(dppo)4] displays in solid state high photoluminescence quantum yields ([greater-than-or-equal]67%) and good stability towards oxygen.
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Electrocatalytic hydrogen evolution using amorphous tungsten phosphide nanoparticles

Chem. Commun. - 25 August, 2014 - 22:54

Chem. Commun., 2014, 50,11026-11028
DOI: 10.1039/C4CC04709E, CommunicationJoshua M. McEnaney, J. Chance Crompton, Juan F. Callejas, Eric J. Popczun, Carlos G. Read, Nathan S. Lewis, Raymond E. Schaak
Amorphous tungsten phosphide, as colloidally synthesized nanoparticles, is an active electrocatalyst for the hydrogen-evolution reaction in acidic aqueous solutions.
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Cyclometalated Ir(III) complexes as targeted theranostic anticancer therapeutics: combining HDAC inhibition with photodynamic therapy

Chem. Commun. - 25 August, 2014 - 22:54

Chem. Commun., 2014, 50,10945-10948
DOI: 10.1039/C4CC05215C, CommunicationRui-Rong Ye, Cai-Ping Tan, Liang He, Mu-He Chen, Liang-Nian Ji, Zong-Wan Mao
A series of phosphorescent Ir(III) complexes as HDACis and photodynamic therapeutic agents have been synthesized and explored for their anticancer mechanisms.
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Modulation of the solubility of luminescent semiconductor nanocrystals through facile surface functionalization

Chem. Commun. - 25 August, 2014 - 22:54

Chem. Commun., 2014, 50,11020-11022
DOI: 10.1039/C4CC03805C, CommunicationTommaso Avellini, Christophe Lincheneau, Marcello La Rosa, Antonio Pertegas, Henk J. Bolink, Iain A. Wright, Edwin C. Constable, Serena Silvi, Alberto Credi
Luminescent quantum dots with programmed solubility in solvents ranging from hexane to water are obtained with a simple and general ligand exchange procedure.
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Revealing the nature of the active site on the carbon catalyst for C-H bond activation

Chem. Commun. - 25 August, 2014 - 22:54

Chem. Commun., 2014, 50,11016-11019
DOI: 10.1039/C4CC02841D, CommunicationXiaoYing Sun, Bo Li, Dangsheng Su
The single ketone group is determined to be the active site in ODH.
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