Royal Society of Chemistry

Ligand-coupling assembly of Re(I)-thiolate complexes

Dalton Transactions - 13 July, 2014 - 18:54

Dalton Trans., 2014, 43,11510-11515
DOI: 10.1039/C4DT00791C, PaperBiing-Chiau Tzeng, An Chao, Manas Banik
Complexes 2 and 4 were synthesized under similar reaction conditions except that different ligands of HNS2 and HNOS, respectively, were used. Two dinuclear structures of 2 and 4 with two similar in situ ligand analogues show distinct conformations, anti and syn forms, respectively.
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One-step fabrication of functionalized magnetic adsorbents with large surface area and their adsorption for dye and heavy metal ions

Dalton Transactions - 13 July, 2014 - 18:54

Dalton Trans., 2014, 43,11637-11645
DOI: 10.1039/C4DT00694A, PaperJianzhi Wang, Guanghui Zhao, Yanfeng Li, Hao Zhu, Xiaomen Peng, Xian Gao
Functionalized magnetic adsorbents were synthesized by a facile and surfactant-free one-pot solvothermal approach, using iron(III) chloride hexahydrate as precursor, ethylene glycol as reducing agent, ammonium acetate, and EDTA-2Na as electrostatic stabilization agent.
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Controlled synthesis and novel luminescence properties of string SrWO4:Eu3+ nanobeans

Dalton Transactions - 13 July, 2014 - 18:54

Dalton Trans., 2014, 43,11493-11501
DOI: 10.1039/C4DT00489B, PaperBingyu Xu, Xi Cao, Guofeng Wang, Ying Li, Yuping Wang, Jiamin Su
String SrWO4:Eu3+ nanobeans were prepared by a hydrothermal method. The effects of the initial reactant content on the phase compositions, morphologies, and luminescence properties of SrWO4:Eu3+ were investigated. Multicolor luminescence tuning of SrWO4:Eu3+ was successfully achieved.
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B2O3-added lithium aluminium germanium phosphate solid electrolyte for Li-O2 rechargeable batteries

Dalton Transactions - 13 July, 2014 - 18:54

Dalton Trans., 2014, 43,11723-11727
DOI: 10.1039/C4DT01144A, PaperHarsharaj S. Jadhav, Ramchandra S. Kalubarme, Seong-Yong Jang, Kyu-Nam Jung, Kyoung-Hee Shin, Chan-Jin Park
B2O3-added Li1.5Al0.5Ge1.5(PO4)3 (LAGP) glass ceramics showing a room temperature ionic conductivity of 0.67 mS cm-1 have been synthesized by using a melt-quenching method.
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Formation of a Eu(III) borate solid species from a weak Eu(III) borate complex in aqueous solution

Dalton Transactions - 13 July, 2014 - 18:54

Dalton Trans., 2014, 43,11516-11528
DOI: 10.1039/C4DT00843J, PaperJuliane Schott, Jerome Kretzschmar, Margret Acker, Sascha Eidner, Michael U. Kumke, Bjorn Drobot, Astrid Barkleit, Steffen Taut, Vinzenz Brendler, Thorsten Stumpf
Using time-resolved laser-induced fluorescence spectroscopy (TRLFS) the transformation of a dissolved Eu(III) borate species into a solid Eu(III) borate was observed.
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An unusual chiral 3D inorganic connectivity featuring a {Pb18} wheel: rapid and highly selective and sensitive sensing of Co(II)

Dalton Transactions - 13 July, 2014 - 18:54

Dalton Trans., 2014, 43,11461-11464
DOI: 10.1039/C4DT00905C, CommunicationYun-Hu Han, Chong-Bin Tian, Shao-Wu Du
Two enantiomorphic frameworks featuring a {Pb18} wheel were produced. They exhibit rapid and highly selective and sensitive sensing of Co2+ ions.
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Magnetic anisotropy in a spin 1/2 quasi-one-dimensional antiferromagnetic copper(II) complex CuCl2(pdz) with a staggered g-tensor

Dalton Transactions - 13 July, 2014 - 18:54

Dalton Trans., 2014, 43,11529-11532
DOI: 10.1039/C4DT00809J, PaperShinya Takaishi, Hiroshi Kitagawa, Hisaaki Tanaka, Shin-ichi Kuroda, Ryuichi Ikeda
We report an unusual magnetic anisotropy in a S = 1/2 1D antiferromagnetic (AF) compound CuCl2(pdz) (pdz = pyridazine).
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The important role of the Mo-Mo quintuple bond in catalytic synthesis of benzene from alkynes. A theoretical study

Dalton Transactions - 13 July, 2014 - 18:54

Dalton Trans., 2014, 43,11478-11492
DOI: 10.1039/C4DT00595C, PaperYue Chen, Shigeyoshi Sakaki
The reaction mechanism of catalytic synthesis of benzene from alkynes by the Mo-Mo quintuple bond and the electronic structure and bonding nature of dimetallacyclobutadiene and dimetallabenzyne were studied theoretically.
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Application of twin screw extrusion to the manufacture of cocrystals: scale-up of AMG 517-sorbic acid cocrystal production

Faraday Disc. - 13 July, 2014 - 06:17
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C3FD00153A, PaperDominick Daurio, Karthik Nagapudi, Lan Li, Peter Quan, Fernando-Alvarez Nunez
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Scale-up of organic reactions in ball mills: process intensification with regard to energy efficiency and economy of scale

Faraday Disc. - 13 July, 2014 - 06:17
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C3FD00144J, PaperAchim Stolle, Robert Schmidt, Katharina Jacob
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Triboelectricity in insulating polymers: evidence for a mechanochemical mechanism

Faraday Disc. - 13 July, 2014 - 06:17
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C3FD00118K, PaperLia Beraldo da Silveira Balestrin, Douglas Del Duque, Douglas Soares da Silva, Fernando Galembeck
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Mechanochemical synthesis of Au, Pd, Ru and Re nanoparticles with lignin as a bio-based reducing agent and stabilizing matrix

Faraday Disc. - 13 July, 2014 - 06:17
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C4FD00053F, PaperMonika J. Rak, Tomislav Friscic, Audrey Moores
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The mechanochemical production of phenyl cations through heterolytic bond scission

Faraday Disc. - 13 July, 2014 - 06:17
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C4FD00027G, PaperTomohiro Shiraki, Charles E. Diesendruck, Jeffrey S. Moore
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Mechanochemical synthesis of an organometallic compound: a high volume manufacturing method

Faraday Disc. - 13 July, 2014 - 06:17
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C3FD00157A, PaperDavid W. Peters, Richard G. Blair
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Quantitative in situ and real-time monitoring of mechanochemical reactions

Faraday Disc. - 13 July, 2014 - 06:17
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C4FD00013G, PaperIvan Halasz, Tomislav Friscic, Simon A. J. Kimber, Krunoslav Uzarevic, Andreas Puskaric, Cristina Mottillo, Patrick Julien, Vjekoslav Strukil, Veijo Honkimaki, Robert E. Dinnebier
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The two-step mechanochemical synthesis of porphyrins

Faraday Disc. - 13 July, 2014 - 06:17
Faraday Discuss., 2014, Advance Article
DOI: 10.1039/C3FD00140G, PaperHannah Shy, Paula Mackin, Andrea S. Orvieto, Deepa Gharbharan, Geneva R. Peterson, Nick Bampos, Tamara D. Hamilton
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Bioactive glass hybrids: a simple route towards the gelatin-SiO2-CaO system

Chem. Commun. - 12 July, 2014 - 12:54

Chem. Commun., 2014, 50,8701-8704
DOI: 10.1039/C3CC49113G, CommunicationXavier Dieudonne, Valerie Montouillout, Edouard Jallot, Franck Fayon, Jonathan Lao
A schematic view of class II bioactive glass hybrids based on SiO2-CaO-gelatin.
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2D conglomerate crystallization of heptahelicene

Chem. Commun. - 12 July, 2014 - 12:54

Chem. Commun., 2014, 50,8751-8753
DOI: 10.1039/C4CC03574G, CommunicationJohannes Seibel, Laura Zoppi, Karl-Heinz Ernst
Two-dimensional homochiral nucleation and conglomerate crystallization of an unsubstituted all-carbon helicene on a metal surface is observed for the first time.
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Tip-induced C-H activation and oligomerization of thienoanthracenes

Chem. Commun. - 12 July, 2014 - 12:54

Chem. Commun., 2014, 50,8791-8793
DOI: 10.1039/C4CC03719G, CommunicationL. E. Dinca, J. M. MacLeod, J. Lipton-Duffin, C. Fu, D. Ma, D. F. Perepichka, F. Rosei
The tip of a scanning tunneling microscope (STM) can be used to dehydrogenate freely-diffusing tetrathienoanthracene (TTA) molecules on Cu(111), trapping the molecules into metal-coordinated oligomeric structures.
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A novel nanogel-based fluorescent probe for ratiometric detection of intracellular pH values

Chem. Commun. - 12 July, 2014 - 12:54

Chem. Commun., 2014, 50,8787-8790
DOI: 10.1039/C4CC03716B, CommunicationLixia Cao, Xiaoyan Li, Shuangqing Wang, Shayu Li, Yi Li, Guoqiang Yang
A new nanogel indicator (NGI) for ratiometric fluorescent detection of intracellular pH values has been reported. In aqueous solution, the NGI can be used for ratiometric sensing of pH changes with a large hypsochromic shift of 100 nm in the green-red region and reversible. Furthermore, the NGI has been used to calibrate the cytosol pH in living cells.
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