Royal Society of Chemistry

A red phosphor BaTiF6:Mn4+: reaction mechanism, microstructures, optical properties, and applications for white LEDs

Dalton Transactions - 9 June, 2014 - 10:17

Dalton Trans., 2014, 43,9414-9418
DOI: 10.1039/C4DT00781F, CommunicationXianyu Jiang, Zhen Chen, Shaoming Huang, Jiaguo Wang, Yuexiao Pan
Red phosphors BaTiF6:Mn4+ were obtained by etching Ti(OC4H9)4 and TiO2 with BaF2 in HF and a KMnO4 solution. The WLED fabricated with BaTiF6:Mn4+ exhibits a "warm" white light with a color rendering index of 93.13.
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Clathrochelates meet phosphorus: thiophosphorylation of Fe(II) dichloroclathrochelate precursor, synthesis of N,S-donor macrobicyclic ligands and their Pd(II) complexes as potent catalysts of Suzuki cross-coupling reaction

Dalton Transactions - 9 June, 2014 - 10:17

Dalton Trans., 2014, 43,9677-9689
DOI: 10.1039/C3DT53590H, PaperOleg I. Artyushin, Irina L. Odinets, Ekaterina V. Matveeva, Anna V. Vologzhanina, Oleg A. Varzatskii, Sergey E. Lyubimov, Yan Z. Voloshin
Nucleophilic substitution of iron(II) dichloroclathrochelate with diphenylphosphine sulfide under PTC gave the first phosphorylated cage complex.
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Crystal chemistry and luminescence properties of red-emitting CsGd1-xEux(MoO4)2 solid-solution phosphors

Dalton Transactions - 9 June, 2014 - 10:17

Dalton Trans., 2014, 43,9669-9676
DOI: 10.1039/C4DT00339J, PaperPinglu Shi, Zhiguo Xia, Maxim S. Molokeev, Victor V. Atuchin
The crystal structure and red-emitting luminescence properties of scheelite related CsGd1-xEux(MoO4)2 solid-solution phosphors have been investigated.
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Tunable long lasting phosphorescence due to the selective energy transfer from defects to luminescent centres via tunnelling in Mn2+ and Tm3+ co-doped zinc pyrophosphate

Dalton Transactions - 9 June, 2014 - 10:17

Dalton Trans., 2014, 43,9661-9668
DOI: 10.1039/C4DT00223G, PaperRan Pang, Yonglei Jia, Ran Zhao, Haifeng Li, Jipeng Fu, Wenzhi Sun, Lihong Jiang, Su Zhang, Chengyu Li, Qiang Su
Tunable long lasting phosphorescence from blue to NIR are achieved from Zn2(0.97-x)P2O7:0.06Tm3+,2xMn2+ phosphors due to selectively energy transfer.
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In situ decoration of plasmonic Ag nanocrystals on the surface of (BiO)2CO3 hierarchical microspheres for enhanced visible light photocatalysis

Dalton Transactions - 9 June, 2014 - 10:17

Dalton Trans., 2014, 43,9468-9480
DOI: 10.1039/C4DT00427B, PaperFan Dong, Qiuyan Li, Ying Zhou, Yanjun Sun, Haidong Zhang, Zhongbiao Wu
Plasmonic Ag nanocrystals were in situ decorated on 3D (BiO)2CO3 hierarchical microspheres for enhanced visible light photocatalysis and photocurrent generation by a one-pot in situ hydrothermal method.
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A novel route for synthesis of UV-resistant hydrophobic titania-containing silica aerogels by using potassium titanate as precursor

Dalton Transactions - 9 June, 2014 - 10:17

Dalton Trans., 2014, 43,9456-9467
DOI: 10.1039/C3DT53389A, PaperWei Wei, Xiaomeng Lu, Deli Jiang, Zaoxue Yan, Min Chen, Jimin Xie
A simple and one-pot sol-gel method with ion-exchange reaction is employed in the controllable synthesis of titania-containing silica aerogels, which exhibit efficient photocatalytic degradation of Rhodamine B.
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Synthesis and electrochemistry of [small beta]-pyrrole nitro-substituted cobalt(II) porphyrins. The effect of the NO2 group on redox potentials, the electron transfer mechanism and catalytic reduction of molecular oxygen in acidic media

Dalton Transactions - 9 June, 2014 - 10:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01072H, PaperBin Sun, Zhongping Ou, Shuibo Yang, Deying Meng, Guifen Lu, Yuanyuan Fang, Karl M. Kadish
Four cobalt porphyrins were synthesized and characterized as to their electrochemical, spectroelectrochemical and electrocatalytic properties.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Investigation on spin-flip reaction of Re + CH3CN by relativistic density functional theory

Dalton Transactions - 9 June, 2014 - 10:17

Dalton Trans., 2014, 43,9508-9517
DOI: 10.1039/C4DT00193A, PaperYi Xiao, Wen-Xin Ji, Wei-Xu, Xian-Yang Chen, Shu-Guang Wang
The minimal energy reaction pathway of Re + CH3CN has been investigated. The minimal energy crossing point is determined with the help of DFT fractional occupation-number (FON) approach.
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A spin-crossover complex based on a 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) ligand functionalized with a carboxylate group

Dalton Transactions - 9 June, 2014 - 10:17

Dalton Trans., 2014, 43,9406-9409
DOI: 10.1039/C4DT00327F, CommunicationAlexandre Abherve, Miguel Clemente-Leon, Eugenio Coronado, Carlos J. Gomez-Garcia, Maurici Lopez-Jorda
[Fe(bppCOOH)2](ClO4)2 shows an abrupt spin transition (T1/2 = 380 K, TLIESST = 60 K) due to a hydrogen-bonded linear network of complexes.
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The V-shaped polar molecules encapsulated into Cs (10528)-C72: stability and nonlinear optical response

Dalton Transactions - 9 June, 2014 - 10:17

Dalton Trans., 2014, 43,9655-9660
DOI: 10.1039/C3DT53329H, PaperLi-Jie Wang, Rong-Lin Zhong, Shi-Ling Sun, Hong-Liang Xu, Xiu-Mei Pan, Zhong-Min Su
The structures, stability and nonlinear optical properties of the encapsulated fullerenes M2N@C72 (M = Sc or Y, N = S or O) and the pristine cage Cs-C72 (10528) were investigated.
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Synthesis, structure and reactivity of [o-(2,6-diisopropylphenyliminomethinyl)phenyl]selenenyl selenocyanate (RSeSeCN) and related derivatives

Dalton Transactions - 9 June, 2014 - 10:17

Dalton Trans., 2014, 43,9431-9437
DOI: 10.1039/C4DT00157E, PaperPrakul Rakesh, Harkesh B. Singh, Jerry P. Jasinski, James A. Golen
The synthesis, structure and reactivity of stable selenenyl selenocyanates having a strong Se-Se bond are reported.
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Engineering plasmonic metal colloids through composition and structural design

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3823-3834
DOI: 10.1039/C3CS60347D, Tutorial ReviewN. E. Motl, A. F. Smith, C. J. DeSantis, S. E. Skrabalak
This Tutorial Review examines the effects of composition, particle size and shape, overall architecture, and local environment on the optical properties of metal colloids.
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Plasmonic nanomaterials for biodiagnostics

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3835-3853
DOI: 10.1039/C3CS60346F, Tutorial ReviewPhilip D. Howes, Subinoy Rana, Molly M. Stevens
We discuss plasmonic nanomaterials as biodiagnostic tools, and how their properties yield tunable optical signals and surface enhanced Raman signals.
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Nanoplasmonics

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3820-3822
DOI: 10.1039/C4CS90026J, EditorialLuis M. Liz-Marzan, Catherine J. Murphy, Jianfang Wang
Guest editors Luis Liz-Marzan, Catherine Murphy and Jianfang Wang introduce the Nanoplasmonics themed issue of Chemical Society Reviews.
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Optical absorption and scattering spectroscopies of single nano-objects

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3921-3956
DOI: 10.1039/C3CS60367A, Review ArticleAurelien Crut, Paolo Maioli, Natalia Del Fatti, Fabrice Vallee
This review focuses on optical detection and spectroscopy of single nano-objects for nanophysics investigation.
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Mapping plasmons at the nanometer scale in an electron microscope

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3865-3883
DOI: 10.1039/C3CS60478K, Tutorial ReviewMathieu Kociak, Odile Stephan
EELS and cathodoluminescence are highly relevant tools to map plasmons within metallic nanoparticles much smaller than the wavelength of light.
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Self-assembled plasmonic nanostructures

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3976-3991
DOI: 10.1039/C3CS60341E, Review ArticleAnna Klinkova, Rachelle M. Choueiri, Eugenia Kumacheva
This review highlights recent advances in the field of self-assembled plasmonic nanostructures, their optical properties and applications.
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Heavily-doped colloidal semiconductor and metal oxide nanocrystals: an emerging new class of plasmonic nanomaterials

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3908-3920
DOI: 10.1039/C3CS60417A, Tutorial ReviewXin Liu, Mark T. Swihart
A new class of plasmonic nanomaterials, based upon heavily-doped semiconductors and metal oxides, is rapidly developing and showing great promise for biomedical and optoelectronic applications.
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Nanoplasmonics for chemistry

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3898-3907
DOI: 10.1039/C3CS60364D, Tutorial ReviewGuillaume Baffou, Romain Quidant
We discuss how nanoplasmonics can benefit chemistry and review the most recent developments in this new and fast growing field of research.
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New materials for tunable plasmonic colloidal nanocrystals

Chem. Soc. Rev. - 9 June, 2014 - 00:17

Chem. Soc. Rev., 2014, 43,3957-3975
DOI: 10.1039/C3CS60265F, Review ArticleAlberto Comin, Liberato Manna
We present a review on the emerging materials for novel plasmonic colloidal nanocrystals.
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