Royal Society of Chemistry

Contributors to the emerging investigators issue 2014

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6482-6484
DOI: 10.1039/C4CS90064B, Profile
Chemical Society Reviews profiles the Emerging Investigators featuring work in this issue.
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Trianionic pincer and pincer-type metal complexes and catalysts

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6325-6369
DOI: 10.1039/C4CS00111G, Review ArticleMatthew E. O'Reilly, Adam S. Veige
This review provides a comprehensive examination of the synthesis, characterization, properties, and catalytic applications of trianionic pincer metal complexes.
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Yellow/orange emissive heavy-metal complexes as phosphors in monochromatic and white organic light-emitting devices

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6439-6469
DOI: 10.1039/C4CS00110A, Review ArticleCong Fan, Chuluo Yang
This article reviews the development of the yellow/orange emissive heavy-metal complexes used in organic light-emitting devices.
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Design, synthesis and excited-state properties of mononuclear Ru(II) complexes of tridentate heterocyclic ligands

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6184-6197
DOI: 10.1039/C4CS00123K, Tutorial ReviewAmlan K. Pal, Garry S. Hanan
Mononuclear Ru(II) complexes of tridentate ligands now exhibit long excited-state lifetimes at room temperature.
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Oxidative etching for controlled synthesis of metal nanocrystals: atomic addition and subtraction

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6288-6310
DOI: 10.1039/C4CS00136B, Review ArticleRan Long, Shan Zhou, Benjamin J. Wiley, Yujie Xiong
This review outlines recent progress in oxidative etching that has provided highly important opportunities for controlled synthesis of metal nanocrystals.
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Nanoscopic optical rulers beyond the FRET distance limit: fundamentals and applications

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6370-6404
DOI: 10.1039/C3CS60476D, Review ArticleParesh Chandra Ray, Zhen Fan, Rebecca A. Crouch, Sudarson Sekhar Sinha, Avijit Pramanik
This review reports recent advances in the development of long-range nanomaterial-based optical rulers.
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Enzyme-assisted target recycling (EATR) for nucleic acid detection

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6405-6438
DOI: 10.1039/C4CS00083H, Review ArticleYulia V. Gerasimova, Dmitry M. Kolpashchikov
Enzyme-assisted target recycling (EATR) is a signal amplification technique that can find application in PCR-free nucleic acid detection.
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Phyllobilins - the abundant bilin-type tetrapyrrolic catabolites of the green plant pigment chlorophyll

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6227-6238
DOI: 10.1039/C4CS00079J, Tutorial ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Bernhard Krautler
Phyllobilins, the bilin-type chlorophyll catabolites, are a hardly known class of abundant linear tetrapyrroles in de-greening leaves and ripening fruit.
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Point-of-care biochemical assays using gold nanoparticle-implemented microfluidics

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6239-6253
DOI: 10.1039/C4CS00125G, Tutorial ReviewJiashu Sun, Yunlei Xianyu, Xingyu Jiang
This review focuses on assaying biomarkers using both gold nanoparticles and microfluidic devices.
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Neutral CH and cationic CH donor groups as anion receptors

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6198-6213
DOI: 10.1039/C4CS00115J, Tutorial ReviewJiajia Cai, Jonathan L. Sessler
Neutral and cationic CH hydrogen bond donors have been actively used in various shape persistent macrocycles, foldamers and "molecular machines".
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Transition metal-mediated bioorthogonal protein chemistry in living cells

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6511-6526
DOI: 10.1039/C4CS00117F, Review ArticleMaiyun Yang, Jie Li, Peng R. Chen
Transition metal-mediated chemical conversions have rapidly expanded our intracellular protein chemistry toolbox, which would broaden our view on bioorthogonal chemistry.
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Organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium or azolium enolates

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6214-6226
DOI: 10.1039/C4CS00042K, Tutorial ReviewLouis C. Morrill, Andrew D. Smith
This tutorial review highlights the organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium/azolium enolates.
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Pyrene-fused pyrazaacenes: from small molecules to nanoribbons

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6311-6324
DOI: 10.1039/C4CS00119B, Review ArticleAurelio Mateo-Alonso
This review covers most of the synthetic and application aspects of pyrene-fused pyrazaacenes from 1937 to our days, illustrating that pyrene-fused pyrazaacenes are a widely tuneable and a highly stable platform for developing ribbon-like nitrogenated polycyclic aromatic hydrocarbons for a broad spectrum of applications.
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An atlas of two-dimensional materials

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6537-6554
DOI: 10.1039/C4CS00102H, Review ArticlePere Miro, Martha Audiffred, Thomas Heine
The discovery of graphene and other two-dimensional (2D) materials together with recent advances in exfoliation techniques have set the foundations for the manufacturing of single layered sheets from any layered 3D material.
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Near-infrared light-responsive nanomaterials in cancer therapeutics

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6254-6287
DOI: 10.1039/C4CS00011K, Review ArticleVijayakumar Shanmugam, S. Selvakumar, Chen-Sheng Yeh
Near-infrared light sensitive nanomaterials provide ideal nanoplatforms in site specific noninvasive cancer therapy.
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Polymer-encapsulated organic nanoparticles for fluorescence and photoacoustic imaging

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6570-6597
DOI: 10.1039/C4CS00014E, Review ArticleOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Kai Li, Bin Liu
In this Critical Review, we summarize the latest advances in the development of polymer encapsulated nanoparticles based on conjugated polymers and fluorogens with aggregation induced emission (AIE) characteristics, elucidate the importance of matrix selection and structure-property relationship of these nanoparticles and discuss their applications in fluorescence and photoacoustic imaging.
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Addition of CF3 across unsaturated moieties: a powerful functionalization tool

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6598-6608
DOI: 10.1039/C4CS00025K, Review ArticleOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Estibaliz Merino, Cristina Nevado
This review summarizes recent methodologies for the simultaneous formation of C-CF3 and C-C or C-heteroatom bonds by formal addition reactions to alkenes.
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Natural and engineered biosynthesis of fluorinated natural products

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6527-6536
DOI: 10.1039/C4CS00027G, Review ArticleMark C. Walker, Michelle C. Y. Chang
Studying the biosynthesis of naturally-occurring and engineered organofluorine natural products may enable the development of new bioactive small molecules.
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Experiment and computation: a combined approach to study the reactivity of palladium complexes in oxidation states 0 to IV

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6609-6638
DOI: 10.1039/C4CS00061G, Review ArticleKarl J. Bonney, Franziska Schoenebeck
This review emphasises the power of combining computation and experiment in the mechanistic study and reactivity design of palladium-mediated chemistry.
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The chemistry of cationic polyphosphorus cages - syntheses, structure and reactivity

Chem. Soc. Rev. - 28 August, 2014 - 20:17

Chem. Soc. Rev., 2014, 43,6639-6657
DOI: 10.1039/C4CS00019F, Review ArticleMichael H. Holthausen, Jan J. Weigand
The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages.
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