Royal Society of Chemistry

An Interlaced Silver Vanadium Oxide-Graphene Hybrid with High Structural Stability for Use in Lithium Ion Batteries

Chem. Commun. - 1 September, 2014 - 02:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC05065G, CommunicationJiwen Qin, Wei Lv, Zhengjie Li, Baohua Li, Feiyu Kang, Quan-Hong Yang
A silver vanadium oxide (SVO) material with an interlaced structure was prepared using graphene as a two-dimensional substrate that directs the crystal growth in the hydrothermal process. The obtained SVO-graphene...
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Porosity control in mesoporous polymers using CO2-swollen block copolymer micelles as templates and their use as catalyst supports

Chem. Commun. - 1 September, 2014 - 02:17

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC05138F, CommunicationLi Peng, Jianling Zhang, Shuliang Yang, Buxing Han, Xinxin Sang, Chengcheng Liu, Guanying Yang
Mesoporous polymers with tunable large mesopores (14-22 nm) were synthesized through a CO2-swollen micelle templating route.
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Crystal Chemical Characteristics of Ellestadite-type Apatite: Implications for Toxic Metal Immobilization

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02088J, PaperYanan FANG, Clemens Ritter, T. White
The ellestadite apatites Ca10[(SiO4)x(PO4)6-2x(SO4)x]Cl2 were studied by powder X-ray and neutron diffraction to establish baseline crystallographic data. These synthetic materials, unlike mineral specimens that are well equilibrated, show no Si/P/S...
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Cyclopalladation of telluro ether ligands: Synthesis, reactivity and structural characterization

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02200A, PaperVimal K Jain, Siddhartha Kolay, Mukesh Kumar, Amey Wadawale, Dasarathi Das
Treatment of [PdCl2(PhCN)2] with diaryl telluride in 1:2 molar ratio gave mononuclear palladium complexes, trans-[PdCl2(TeR2)2] (1) (R = Mes (1a) (Mes = 2,4,6-trimethylphenyl), Ph (1b), o-tol (1c) (o-tol = ortho-tolyl))....
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Synthesis, Structure and Spectral and Electrochemical Properties of 3-Pyrrolyl BODIPY-Metal Dipyrrin Complexes

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01970A, PaperMagalampalli Ravikanth, Lakshmi Vellanki, Way-Zen Lee
The stable dipyrrin substituted 3-pyrrolyl BODIPY (-dipyrrin 3-pyrrolyl BODIPY) was synthesized by oxidation of dipyyromethane substituted 3-pyrrolyl BODIPY with 2,3-dichloro-5,6-dicyano-benzoquinone in CH2Cl2 at room temperature. The -dipyrrin 3-pyrrolyl BODIPY is...
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New 'Aggregation Induced Emission (AIE)' Active Cyclometalated Iridium(III) Based Fluorescent Sensors: High Sensitivity for Mercury(II) Ions

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02266A, PaperInamur Rahaman Laskar, parvej alam, Gurpreet Kaur, Angshuman Roychoudhury, Pere Alemany, saleem pasha, Claudia Climent, David Casanova
Design and syntheses of 'Aggregation Induced Emission (AIE)' active blue-emitting bis-cyclometalated iridium(III)complexes with appended diphosphine ligands [Ir(F2ppy)2(L1/L2)2(Cl)] (F2ppy=2-(2[prime or minute],4[prime or minute]-difluoro) phenylpyridine; L1 = 1,2-bis(diphenylphosphino)ethane; L2 = bis(diphenylphosphino)propane) have been realized on a...
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Down-shifting and upconversion photoluminescence in Ho3+/Yb3+ co-doped GdNbO4: effect of Bi3+ ion and magnetic field

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01864H, PaperAbhishek Dwivedi, Akhilesh Kumar Singh, S. B. Rai
A green emitting Gd(0.95-x)HoxYb0.05NbO4 phosphor (x= 0.001, 0.005, 0.01, 0.02, 0.03 and 0.035) has been synthesized by solid-state reaction method. The phosphor samples were characterized by X-ray diffraction (XRD), Fourier...
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Synthesis of tetra-substituted imidazoles and 2-imidazolines by Ni(0)-catalyzed dehydrogenation of benzylic-type imines

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02313G, PaperAdrian Tlahuext-Aca, Oscar Hernandez-Fajardo, Alma Arevalo, Juve Garcia
Ni(0)-catalyzed dehydrogenation of benzylic-type imines was performed to yield asymmetrical tetra-substituted imidazoles and 2-imidazolines. This was achieved with a single operational step while maintaining good selectivity and atom economy. The...
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Synthesis and crystal structure of a series of incommensurately modulated composite oxohalide compounds

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02084G, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Iwan Zimmermann, Alexis Corgnet, Mats Johnsson, Sven Lidin
Transparent needle like single crystals of the isostructural compounds [Sb4O7+3[small delta]X4][Zn3]1+[small delta](X = Cl, Br, I), [small delta][approximate] 0.2 were obtained from chemical reactions in evacuated and sealed silica tubes. First the average...
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Crystal structure, DFT, spectroscopic and biological activity evaluation of analgin complexes with Co(II), Ni(II) and Cu(II)

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02366H, PaperAhmed Moustafa Mansour
Reaction of analgin (NaL) with Co(II), Ni(II) and Cu(II) salts in ethanol affords complexes of the type [ML2], which were characterized by elemental analysis, FT IR, UV-Vis., EPR, TG/DTA, magnetic...
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Electrochemical Fluorination of perovskite type BaFeO2.5

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02485K, PaperOliver Clemens, Carine Rongeat, Munnangi Anji Reddy, Andreas Giehr, Maximilian Fichtner, Horst Hahn
Here we report on the first electrochemical fluorination exemplarily performed on perovskite type BaFeO2.5. A cell setup of the type BaFeO2.5 II La0.9Ba0.1F2.9 II MFx (with MFx being MgF2 and...
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Selective Synthesis of Cis- and Trans-[(NHCMe)2PtCl2] and [NHCMePt(cod)Cl][NHCMePtCl3] using NHCMeSiCl4

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02214A, CommunicationLesley Cherise Lewis-Alleyne, Bassem Basil, Tobias Bottcher, Gerd-Volker Roschenthaler
NHCMeSiCl4, (NHCMe = 1,3-dimethylimidazolidin-2-ylidene), was used to synthesise novel NHCMe-Pt(II) complexes. An atypical trans-cis isomerisation process has also been achieved for [Pt(NHCMe)2Cl2], while the synthesis of the unique double-complex salt,...
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Reactivity of Boryllithium with AlMe3, AlEt3, and GaMe3, including the Synthesis of a Lanthanum Heterogallate Complex

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02155J, PaperReiner Anwander, Nicole Dettenrieder, Christoph Schadle, Caecilia Maichle-moessmer
Treatment of boryllithium (THF)2Li[B(NDippCH)2] (Dipp = 2,6-diisopropylphenyl) with various amounts of AlMe3 or GaMe3 leads to the formation of inter group 13 compounds. Equimolar reactions result in ate complexes of...
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Structural diversity and Magenetic Properties of Six Metal-Organic Polymers Based on Semirigid Tricarboxylate Ligand of 3,5-Bi(4-carboxyphenoxy)benzoic Acid

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01953A, Paperxiutang zhang, Weiliu Fan, Weikuo Song, Liming Sun, Xian Zhao, Liming Fan
Solvothermal reactions of the semirigid 3,5-bi(4-carboxyphenoxy)benzoic acid (H3BCP) and transitional metal cations with the help of three ancillary bridging imidazole linkers afford six coordination polymers, namely, [Co(HBCP)(1,4-bib)0.5]n (1), {[Mn1.5(BCP)(1,4-bib)0.5([small mu ]2-H2O)(H2O)2][round bullet, filled](1,4-bib)0.5}n (2),...
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Synthesis, Magnetism and Mossbauer Studies of Tetranuclear Heterometallic {FeIII2Ln2}(Ln = Gd, Dy,Tb) Complexes: Evidence of Slow Relaxation of Magnetization in the Terbium Analogue

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01451K, PaperVadapalli Chandrasekhar, Prasenjit Bag, Joydeb Goura, Valeriu Mereacre, Ghenadie Novitchi, Annie K Powell
A new family of tetranuclear heterometallic assemblies, [FeIII2Gd2(H2L)4([small eta]2-NO3)2][round bullet, filled]2ClO4∙2CH3OH∙2H2O (1), [FeIII2Dy2(H2L)4([small eta]2-NO3)2][round bullet, filled]2ClO4∙2CH3OH∙2H2O (2), [FeIII2Tb2(H2L)4([small eta]2-NO3)2][round bullet, filled]2ClO4∙2CH3OH∙2H2O (3) have been successfully synthesized employing a multidentate Schiff-base ligand, (E)-2,2'-(2-hydroxy-3-((2-hydroxyphenylimino)methyl)-5-methylbenzylazanediyl)-diethanol (H4L), Fe(ClO4)2.6H2O and LnIII nitrate salts. These...
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Crystal Structure and Magnetic Properties of a Zintl Phase EuIrIn4: The First Member in the Eu-Ir-In Family

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01620C, PaperSebastian Chirambatte Peter, Matthias J Gutmann, Sumanta Sarkar
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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pH-dependent assembly of two polyoxometalate host-guest structural isomers based on keggin polyoxoanion templates

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02050B, PaperLei Zhang, Wenbin Yang, Xiaofei Kuang, Xiao-Yuan Wu, Can-Zhong Lu
Two interesting polyoxometalate-templated host-guest compounds 1 and 2 with the same chemical formulae of [Ag6(tpt)4(SiW12O40)Cl2][round bullet, filled]2H2O have been obtained by the hydrothermal reactions of monlacunary Keggin-type K8[[small alpha]-SiW11O39][round bullet, filled]13H2O with CH3COOAg and tpt...
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Probing the photophysical capability of mono and bis(cyclometallated) Fe(II) polypyridine complexes using inexpensive ground state DFT

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01939C, PaperIsabelle M. DIXON, Sheryar Khan, Fabienne Alary, Martial Boggio-Pasqua, Jean-Louis Heully
The abundance and low toxicity of iron with respect to ruthenium would certainly make it inescapable for photophysical applications if one could circumvent its tendency to make high-spin compounds and...
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Coordination chemistry of Co complexes containing tridentate SNS ligands and their application as catalysts for the oxidation of n-octane

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01750A, PaperLynette Soobramoney, Muhammad Bala, Holger B Friedrich
The selective oxidation of saturated hydrocarbons to terminal oxygenates under mild catalytic conditions has remained a centuries long challenge to chemical catalysis. In an attempt to address this challenge, two...
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Synthesis of novel and stable g-C3N4/N-doped SrTiO3 hybrid nanocomposites with improved photocurrent and photocatalytic activity under visible light irradiation

Dalton Transactions - 31 August, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01076K, PaperSantosh Kumar, Surendar T, Arabinda Baruah, Bharat Kumar, Vishnu Shanker
The hybrid nanocomposites based on N-doped SrTiO3 nanoparticles wrapped g-C3N4 nanosheets were prepared by a facile and reproducible polymeric citrate and thermal exfoliation method. The results clearly indicated that the...
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