Royal Society of Chemistry

Structural limitations for optimizing garnet-type solid electrolytes: A perspective

Dalton Transactions - 22 September, 2014 - 13:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02162B, PerspectiveWolfgang Zeier
Lithium ion batteries exhibit the highest energy densities of all battery types and are therefore an important technology for energy storage in every day life. Today's commercially available batteries employ...
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Synthesis and Order-Disorder Transition in Novel Metal Formate Framework of [(CH3)2NH2]Na0.5Fe0.5(HCOO)3]

Dalton Transactions - 22 September, 2014 - 13:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02586E, PaperMiroslaw Maczka, Adam Pietraszko, L. Macalik, Adam Sieradzki, Justyna Trzmiel, Adam Pikul
We report the synthesis, crystal structure, thermal, dielectric, Raman, infrared, and magnetic properties of [(CH3)2NH2][Na0.5Fe0.5(HCOO)3] (DMNaFe), the first metal formate framework templated by organic cations, presenting an ABO3 perovskite architecture...
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Controlled Synthesis and Characterization of the Elusive Thiolated Ag55 Cluster

Dalton Transactions - 22 September, 2014 - 13:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02476A, CommunicationIndranath Chakraborty, Shrabani Mahata, Anuradha Mitra, Goutam De, T. Pradeep
A stable, Ag55 cluster protected with 4-(tert-butyl) benzyl mercaptan (BBSH) was synthesized which exhibits two prominent absorption bands with maxima at 2.25 and 2.81 eV. A molecular ion peak at...
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Atomic Layer Deposition of Sodium and Potassium Oxides: Evaluation of Precursors and Deposition of Thin Films

Dalton Transactions - 22 September, 2014 - 13:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01930J, PaperErik Ostreng, Henrik Hovde Sonsteby, Sigurd Oien, Ola Nilsen, Helmer Fjellvag
Thin films of sodium and potassium oxides have for the first time been deposited using atomic layer deposition. Sodium and potassium complexes of tert-butanol, trimethylsilanol and hexamethyldisilazane have been evaluated...
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Enantiopure N,N,O-Scorpionate Zinc Amide and Chloride Complexes as Efficient Initiators for the Heteroselective ROP of Cyclic Esters.

Dalton Transactions - 22 September, 2014 - 13:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02178A, PaperAntonio Otero, manuel honrado, juan fernandez, LUIS FERNANDO SANCHEZ-BARBA MERLO, andres garces, agustin lara, Ana Maria Rodriguez
The reaction of bpzbeH, bpzteH (racemic mixture) or (R,R)-bpzmmH (enantiopure) with the amide complexes Zn{N(SiMe3)2}2 or Zn{N(SiHMe2)2}2 in a 1:1 molar ratio in toluene afforded the mononuclear amide zinc complexes...
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Time- resolved and photoluminescence spectroscopy of [small theta]-Al2O3 nanowires for promising fast optical sensor applications

Dalton Transactions - 22 September, 2014 - 13:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01831A, PaperJitendra Gangwar, BIPIN KUMAR GUPTA, Pawan Kumar, Surya Kant Tripathi, Avanish kumar Srivastava
Herein, we have demonstrated the high yield facile growth of uniform morphology with different polymorphs phases (e.g. [gamma], [small delta] and [small theta]) of Al2O3 nanowires via a hydrothermal method with varying...
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Sonochemical Redox Reactions of Pu(III) and Pu(IV) in Aqueous Nitric Solutions

Dalton Transactions - 22 September, 2014 - 13:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02330G, PaperMatthieu Virot, Laurent Venault, Philippe Moisy, Sergey Nikitenko
The behavior of Pu(IV) and Pu(III) was investigated in aqueous nitric solutions under ultrasound irradiation (Ar, 20 kHz). In the absence of anti-nitrous reagents, ultrasound has no effect toward Pu(IV)...
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Si(SiMe3)2SiPh3 - a ligand for novel sub-valent tin cluster compounds

Dalton Transactions - 22 September, 2014 - 13:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02372B, PaperR. Klink, C. Schrenk, A. Schnepf
[Si(SiMe3)2(SiPh3)]- can be used as a ligand in subvalent tin chemistry as shown by the synthesis of [Sn(Si(SiMe3)2SiPh3)2Cl]- and Cl4Sn4[Si(SiMe3)2SiPh3]4.
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Structural modulation in two CuII-based MOFs by synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect

Dalton Transactions - 22 September, 2014 - 13:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02321H, CommunicationYun-Wu Li, Da-Cheng Li, Jian Xu, Hong-Guo Hao, Su-Na Wang, Jian-Min Dou, Tong-Liang Hu, Xian-He Bu
A synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect was successfully applied to tune two CuII-based MOFs. 1 represents a cds topology, while 2 is built by three distinct {Cu4} clusters as SBUs.
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Photoinduced hydrogen evolution by a pentapyridine cobalt complex: elucidating some mechanistic aspects

Dalton Transactions - 22 September, 2014 - 13:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02269F, PaperElisa Deponti, Alessandra Luisa, Mirco Natali, Elisabetta Iengo, Franco Scandola
The ability of a new pentapyridine cobalt(II) complex to power photochemical hydrogen evolution from water is investigated in detail.
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Bis(acetylacetonato)bis(pyrazolato)ruthenate(III) as a redox-active scorpionate ligand

Dalton Transactions - 22 September, 2014 - 13:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02331E, PaperJun Yoshida, Keisuke Sugawara, Hidetaka Yuge, Jun Okabayashi
The octahedral Ru(III) complex acts as a redox-active scorpionate ligand.
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Crystal chemical characteristics of ellestadite-type apatite: implications for toxic metal immobilization

Dalton Transactions - 22 September, 2014 - 13:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02088J, PaperY. N. Fang, Clemens Ritter, T. J. White
Ellestadites are silicate-sulphate apatite matrices for the immobilization of toxic metal waste. Phosphate-rich chlorellestadite, Ca10[(SiO4)x(PO4)6-2x(SO4)x]Cl2 (0 [less-than-or-equal] x [less-than-or-equal] 1) show promise as ceramic waste forms for hazardous fly ashes rich in sulphur and chlorine.
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Nickel promoted functionalization of CO2 to anhydrides and ketoacids

Dalton Transactions - 22 September, 2014 - 13:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01221F, PaperZoe R. Greenburg, Dong Jin, Paul G. Williard, Wesley H. Bernskoetter
Nickel pyridyl-phosphine species couple CO2 with olefins and can produce cyclic anhydrides and ketoacids with alkyl zinc and/or carbon monoxide.
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Tri- and tetra-dentate imine vanadyl complexes: Synthesis, structure and ethylene polymerization/ring opening polymerization capability

Dalton Transactions - 22 September, 2014 - 13:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01448K, PaperCarl Redshaw, Jing Ma, Keqing Zhao, Mark Walton, Joseph A Wright, David L. Hughes, Mark Robert James Elsegood, Xinsen Sun, Kenji Michiue
Reaction of the ligand 2,4-tert-butyl-6-[(2-methylquinolin-8-ylimino)methyl]phenol (L1H) with [VOCl3] in the presence of triethylamine afforded the complex [VOCl2L1] (1), whereas use of [VO(OnPr)3] led to the isolation of [VO2L1] (2) or...
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Two Strandberg-type organophosphomolybdates: synthesis, crystal structure and catalytic properties

Dalton Transactions - 22 September, 2014 - 13:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02571G, PaperJian Ping Wang, Hong-Xin Ma, Lan-Cui Zhang, wansheng You, Zaiming Zhu
Two novel Strandberg-type organophosphomolybdate hybrid compounds [(Cu(H2O))2(-bipy)2(C6H5PO3)2Mo5O15]n (1) and [(Cu(H2O)2)2(-bipy)(C6H5PO3)2Mo5O15]n (2) (bipy =4,4'-bipyridyl) were prepared by mild hydrothermal conditions and structurally characterized by physico-chemical and spectroscopic methods. Single crystal X-ray...
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Gold(I)Thiolates Containing Amino Acid Moieties. Cytotoxicity and Structure-Activity Relationship Studies

Dalton Transactions - 22 September, 2014 - 13:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02299H, PaperM Concepcion Gimeno, Alejandro Gutierrez, Lucia Gracia-Fleta, Isabel Marzo, Carlos Cativiela, Antonio Laguna
Several gold(I) complexes containing a thiolate ligand functionalised with several amino acid or peptide moieties of the type [Au(SPyCOR)(PPh2R´)] (where R = OH, amino acid or dipeptide and R´ =...
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Niobium(V) and tantalum(V) halide chalcogenoether complexes - towards single source CVD precursors for ME2 thin films

Dalton Transactions - 22 September, 2014 - 13:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02694B, Papersophie louise Benjamin, Yao-Pang Chang, Chitra Gurnani, Andrew L Hector, Michelle Huggon, W Levason, Gillian Reid
A series of pentavalent niobium and tantalum halide complexes with thio-, seleno- and telluro-ether ligands, [MCl5(EnBu2)] (M = Nb, Ta; E = S, Se, Te), [TaX5(TeMe2)] (X = Cl, Br,...
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The Strength of Actinide-Element Bonds from the Quantum Theory of Atoms in Molecules

Dalton Transactions - 22 September, 2014 - 13:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02323D, PaperQian-Rui Huang, Jennifer Kingham, Nikolas Kaltsoyannis
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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A flexible zwitterion-ligand based lanthanide metal-organic framework for luminescence sensing of metal ion and small molecules

Dalton Transactions - 22 September, 2014 - 13:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02445A, CommunicationRong-Mei Wen, Song-De Han, Guo-Jian Ren, Ze Chang, Yunwu Li, Xian-He Bu
A new lanthanide metal-organic framework has been constructed by using a tripodal flexible zwitterion (H3LBr3) ligand which taking chair-shaped configuration. The luminescence of the compound displays highly selective sensing of...
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Polyoxometalate-based complex with visible-light photochromism as electrocatalyst for generating hydrogen from water

Dalton Transactions - 22 September, 2014 - 13:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01685H, PaperYun Gong, Yong Xi Yang, Miao M Zhang, Xiao Lin Gao, Jun Li Yin, Jian Hua Lin
Two polyoxometalate (POM)-based complexes formulated as (HL1)2(Mo8O26)[middle dot]2HL1 [middle dot]11H2O (L1 = 3- (5- (1H -pyrazol -4 -yl) -1H -1,2,4 -triazol -3 -yl) pyridine) (1) and Co2(L2)4[P2MoVI5O23MoII(H2O)2][middle dot]3H2O (L2 = 4-(5-(2H-1,2,4-triazol-3 -yl) -2H...
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