Royal Society of Chemistry

Spin canting, metamagnetism, and single-chain magnetic behaviour in a cyano-bridged homospin iron(II) compound

Chem. Commun. - 27 February, 2015 - 21:54

Chem. Commun., 2015, 51,4360-4363
DOI: 10.1039/C4CC10003D, CommunicationDong Shao, Shao-Liang Zhang, Xin-Hua Zhao, Xin-Yi Wang
A cyano-bridged FeII compound exhibiting the coexistence of spin canting, antiferromagnetic ordering, metamagnetism and single-chain magnetism was reported.
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Synthesis, structure and properties of C3-symmetric heterosuperbenzene with three BN units

Chem. Commun. - 27 February, 2015 - 21:54

Chem. Commun., 2015, 51,4368-4371
DOI: 10.1039/C4CC10105G, CommunicationXiao-Ye Wang, Fang-Dong Zhuang, Xin-Chang Wang, Xiao-Yu Cao, Jie-Yu Wang, Jian Pei
The first parent skeleton of BN heterocoronene with three BN units and C3 symmetry was synthesized as a model compound of BN-doped graphene.
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A high performance O2 selective membrane based on CAU-1-NH2@polydopamine and the PMMA polymer for Li-air batteries

Chem. Commun. - 27 February, 2015 - 21:54

Chem. Commun., 2015, 51,4364-4367
DOI: 10.1039/C4CC09281C, CommunicationLujie Cao, Fucong Lv, Ying Liu, Wenxi Wang, Yifeng Huo, Xianzhu Fu, Rong Sun, Zhouguang Lu
A novel oxygen selective membrane was prepared and assembled in Li-air batteries operating under real air conditions with 30% RH. Due to its high O2 permeability, remarkable CO2 capture ability and excellent hydrophobic behavior, extremely stable cycling performance was achieved.
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An Exhibition of the Bronsted Acid-Base Character by a Schiff Base in Palladium(II) Complex Formation: Lithium Complex, Fluxional Property and Catalysis of Suzuki Reactions in Water

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00438A, PaperGanesan Mani, Rajnish Kumar
The reaction of the dialdehyde N,N-di([small alpha]-formylpyrrolyl-[small alpha]-methyl)-N-methylamine 1 with two equiv of 2,6-diisopropylanilline yielded two Schiff bases: bis(iminopyrrolylmethyl)amine (H2L) and its hydrolyzed monoimino compound (H2L') after column separation. The dimeric lithium...
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Fabrication of Ultrathin CoMoO4 Nanosheet Modified with Chitosan and their Improved Performance in Energy Storage Device

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00622H, PaperRamya Ramkumar, Manickam Meenakshi
Ultrathin nanosheet-assembled cobalt molybdate (CoMoO4) owing to the mesoporous morphology was synthesized by urea-assisted solution combustion route at a temperature of 400 ᵒC. The as-prepared CoMoO4 was modified using chitosan...
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Ni/Ti layered double hydroxide: Synthesis, characterization and application as a photocatalyst for visible light degradation of aqueous methylene blue

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00257E, PaperKrishna Gopal Bhattacharyya, Priyadarshi Roy Chowdhury
Visible light responsive 2:1 Ni/Ti layered double hydroxide (LDH) was synthesized by a single step hydrothermal route using commercially available Ni(NO3)2.6H2O, TiCl4 and urea. The material exhibited significant absorption in...
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Exposing the Intermolecular Nature of the Second Relaxation Pathway in a Cobalt(II) Single-Ion Magnet with Positive Anisotropy

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00258C, PaperFatemah Habib, Ilia Korobkov, Muralee Murugesu
The investigation of a pentagonal bipyramidal Co(II) complex with large positive anisotropy (D [approximate] +30 cm-1) revealed field induced Single-Molecule Magnet behaviour with Ueff [approximate] 50 K at 1.0 kOe....
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Palladium(II)-1-phenylthio-2-arylchalcogenoethane complexes: palladium phosphide nano-peanut and ribbon formation controlled by chalcogen and Suzuki coupling activation

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03471F, PaperAjai kumar Singh, Gyandshwar Kumar Rao, Arun Kumar, Fariha Saleem, Mahabir Pratap Singh, Satyendra Kumar, Bharat Kumar, Goutam Mukherjee
The ligands PhSCH2CH2EAr (L1-L3; E = S, Se or Te) and their Pd-complexes [PdLCl2]; (1-3] have been synthesized and authenticated with their 1H, 13C{1H}, 77Se{1H} and 125Te{1H} NMR spectra. Single...
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Nitrogen Enriched Mesoporous Organic Polymer Anchored Copper(II) Material: an Efficient and Reusable Catalyst for the Synthesis of Esters and Amides From aromatic systems

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03838J, PaperRostam Ali Molla, Md. Asif Iqubal, Kajari Ghosh, Kamaluddin Kamal, SM Islam
A new copper-grafted mesoporous poly-melamine-formaldehyde (Cu-mPMF) has been synthesized from melamine and paraformaldehyde in DMSO medium, followed by grafting of Cu(II) at its surface. Cu-mPMF has been characterized by elemental...
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Cyclic tetramers of five-membered palladacycle based on head-to-tail-linked isocyanate dimer and their reactivity in cyclotrimerization of isocyanates

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00534E, PaperYong-Joo Kim, Seon Gye Lee, Keun-Young Choi, SuJin Park, Soonwon Lee
Novel macrocyclic complexes, tetramers of a five-membered ring consisting of an organic isocyanate dimer and palladium, were prepared from bis(phosphine)palladium-styrene and benzyl isocyanate. Isocyanate cyclotrimerization with tetrameric or single palladacycles...
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Copper-Incorporated Mono- and Di-TeRu5 Metal Carbonyl Complexes: Syntheses, Structures, and an Unusual Skeletal Arrangement

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00546A, PaperMinghuey Shieh, Chia-Yeh Miu, Kai-Jieah Hsing, Li-Fing Jang, Chien-Nan Lin
Two sandwich-type Cu3Cl- or Cu2{Te2Ru4(CO)10}-bridging di-TeRu5 clusters, [{TeRu5(CO)14}2Cu3Cl]2─ (1) and [{TeRu5(CO)14}2Cu2{Te2Ru4(CO)10}]4─ (2), were obtained from the reaction of [TeRu5(CO)14]2─ with 1 equiv of [Cu(MeCN)4][BF4] in CH2Cl2 or THF at 0...
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Solvent-free synthesis of new inorganic-organic hybrid solids with finely tuned manganese oxalate structures

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00431D, CommunicationLindong Luan, Jing Li, Changzhen Yin, Zhien Lin, hui huang
Three manganese phosphate-oxalates have been synthesized under solvent-free conditions. These inorganic-organic hybrid solids are based on a pcu-type topology with nanobelt-like, sql-, and cds-type manganese oxalate skeletons, respectively. The amine...
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Synthesis of Cyclic Polyesters: Effects of Alkoxy Side Chain in Salicylaldiminato Tin(II) Complexes

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00139K, PaperPhonpimon Wongmahasirikun, Paweenuch Prom-on, Preeyanuch Sangtrirutnugul, Palangpon Kongsaeree, Khamphee Phomphrai
A new class of salicylaldiminato tin(II) catalysts having different alkoxy side chains has been developed. The ligands were modified to have different length and flexibility as -(CH2)2- (2a), -(CH2)3- (2b),...
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Solvent Effect on the Structures and Magnetic Properties of Two Doubly Interpenetrated Metal-Organic Frameworks

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT04006F, PaperFu-Ping Huang, Cheng Yang, Hai-Ye Li, Peng-Fei Yao, Xiao-Huan Qin, Shi-Ping Yan, Mohamedally Kurmoo
Two doubly interpenetrated coordination polymers [Co2(BDC)2(bpt)2].nSolvent based on dimeric secondary building units and crystallizing with distinct solvent molecules (1-H2O and 2-MeOH for nSolvent = 2H2O and MeOH.H2O, respectively), were obtained...
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In-situ characterization of uranium and americium oxide solid solution formation for CRMP process: first combination of in-situ XRD and XANES measurements

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03515A, PaperMarie Caisso, Sebastien Picart, renaud c belin, Florent LEBRETON, Philippe Martin, Kathy Dardenne, Joerg Rothe, Daniel R. Neuville, THIBAUD DELAHAYE, Andre Ayral
Transmutation of americium in heterogeneous mode through the use of U1-xAmxO2+/-[small delta] ceramic pellets, also known as Americium Bearing Blankets (AmBB), has become a major research axis. Nevertheless, in order to...
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Stepwise assembly of a semiconducting coordination polymer [Cd8S(SPh)14(DMF)(bpy)]n and its photodegradation of organic dyes

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03687E, PaperChao Xu, Niklas Hedin, Hua-Tian Shi, Zhifeng Xin, Qian-Feng Zhang
Chalcogenolate clusters can be interlinked with organic linkers into semiconducting coordination polymers with photocatalytic properties. Here, discrete clusters of Cd8S(SPh)14(DMF)3 were interlinked with 4,4'-bipyridine into a one dimensional coordination polymer...
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An open chain carboxyethyltin functionalized sandwich-type tungstophosphate based on trivacant Dawson subunit: synthesis, characterization and properties

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00361J, Paperjianping Bai, fang Su, Hao-Tian Zhu, hang Sun, Lan-Cui Zhang, Meiying Liu, wansheng You, Zaiming Zhu
A Dawson sandwich-type polyoxometalate {C(NH2)3}12H4[[small alpha][small beta][small beta][small alpha]-{(Sn(C3H4O2))2Mn2(P2W15O56)2}][round bullet, filled]22H2O (Abbreviated as SnR-Mn-P2W15), functionalized by open chain carboxyethyltin groups was first prepared in aqueous solution under conventional reaction conditions, and structurally characterized by physico-chemical and...
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Novel metal-organic framework with tunable fluorescence property: supramolecular signaling platform for polynitrophenolics

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00489F, CommunicationRik Rani Koner, Mangili Venkateswarulu, Avijit Pramanik
With the aid of a rotational C3-symmetric tricarboxytriphenylamine based ligand, a new Cd-MOF was synthesized and characterized by various spectroscopic techniques as well as by single-crystal X-ray diffraction analysis. The...
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An electrochemical aptasensor based on TiO2/three-dimensional reduced graphene oxide/PPy nanocomposite for the sensitive detection of lysozyme

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00168D, PaperMinghua Wang, Shuyong Zhai, Zihan Ye, Linghao He, Donglai Peng, Xiaozhong Feng, Yanqin Yang, shaoming fang, Hongzhong Zhang, Zhihong Zhang
A sensitive aptasensor based on a nanocomposite of hollow titanium dioxide nanoball, three-dimensional reduced graphene oxide, and polypyrrole (TiO2/3D-rGO/PPy) was developed for lysozyme detection. Lysozyme aptamer was easily immobilized onto...
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Synthesis, Structure, and Magnetic Properties of Novel B-site Ordered Double Perovskites, SrLaMReO6 (M = Mg, Mn, Co and Ni)

Dalton Transactions - 27 February, 2015 - 05:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03821E, PaperJohn E Greedan, Corey M. Thompson, Lisheng Chi, Alannah Hallas, Murray Wilson, Timothy Munsie, Ian Swainson, Andrew Paul Grosvenor, John R Hayes, Graeme Luke
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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