Royal Society of Chemistry

White up-conversion luminescence power and efficiency in Yb3+-, Er3+- and Tm3+-doped BaIn6Y2O13

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02312A, PaperJiao Zhang, YanMin Yang, Chao Mi, Yanzhou Liu, Fang Yu, Xiaohong Li, YaoHua Mai
A series of BaIn6Y2O13: Yb3+, Er3+, Tm3+ phosphors with different dopant concentrations have been successfully synthesized by a sol-gel method. In order to obtain efficient white light emitting samples, the...
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Exceptionally Efficient Catalytic Hydrodechlorination of Persistent Organic Pollutants: Application of New Sterically Shielded Palladium Carbene Complexes

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02908A, PaperVagiz Shamilievich Saberov, Daniel A. Evans, Nikolai Ivanovich Korotkikh, Alan H. Cowley , Tatyana Mikhailovna Pekhtereva, Anatolii Fedorovich Popov, Oles Pavlovich Shvaika
A new sterically shielded carbene with branched aromatic substituents (9a) and two palladium halogenide complexes (11a,b) have been prepared. The single crystal X-ray structures of free carbene 9a and palladium...
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Synthesis, Structure and Catalytic Application of Lead(II) Complexes in Cyanosilylation Reaction

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02316A, PaperAnirban Karmakar, Susanta Hazra, M. Fatima C. Guedes da Silva, Armando J L Pombeiro
Hydrothermal reactions of a lead(II) salt with 3-aminopyrazine-2-carboxylic acid (HL1) gave rise to a series of lead(II) coordination compounds (1-6) having zero, one, two and three dimensional structures. X-ray diffraction...
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Multicolor (Vis-NIR) mesoporous silica nanospheres linking with lanthanide complexes by 2-(5-bromothiophen)imidazo[4,5-f][1,10]phenanthroline for in vitro bioimaging

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02444C, PaperYing Liu, Li-Ning Sun, Jinliang Liu, Yu-Xin Peng, Xiaoqian Ge, Liyi Shi, Wei Huang
A novel mesoporous nanosphere functionalized with 3-(aminopropyl)triethoxysilane (APTES) and 2-(5-bromothiophen)imidazo[4,5-f][1,10]phenanthroline (5-Br-Tip) was synthesized (denoted as Tip-MSS). With the coordinating function of the 5-Br-Tip to lanthanide (Ln) ions, for the first...
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Amino acid derived CuII compounds as catalysts for asymmetric oxidative coupling of 2-naphthol

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02731K, PaperPedro Adao, Sonia Barroso, M. Fernanda N.N. Carvalho, Carlos Teixeira, Maxim L. Kuznetsov, Joao Costa Pessoa
We report the synthesis and characterization of several novel aminopyridine - L-amino acid derived CuII-complexes; The ligands are prepared by a one-pot reductive alkylation of the L-amino acid scaffold and...
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Oxidative Halogenation of Cisplatin and Carboplatin: Synthesis, Spectroscopy, and Crystal and Molecular Structures of Pt(IV) Prodrugs

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02627F, PaperStephen J. Lippard, Timothy Johnstone, Justin J Wilson, Sarah M Alexander
A series of Pt(IV) prodrugs has been obtained by oxidative halogenation of either cisplatin or carboplatin. Iodobenzene dichloride is a general reagent that cleanly provides prodrugs bearing axial chlorides without...
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Enhanced visible light photocatalytic activity of ZnO doped with down-conversion NaSrBO3:Tb3+ phosphors

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01252F, CommunicationXinjuan Liu, Xiaojun Wang, Huili Li, Jinliang Li, Likun Pan, Jing Zhang, Guoquan Min, Zhuo Sun, Chang Qing Sun
ZnO-NaSrBO3:Tb3+ (ZNT) composites were successfully synthesized via microwave-assisted reaction of the ZnO precursor with a NaSrBO3:Tb3+ suspension using a microwave synthesis system. The morphology, structure and photocatalytic performance in the...
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Mixed Sandwich Thorium Complexes Incorporating Bis(tri-isopropylsilyl)cyclooctatetraenyl and Pentamethylcyclopentadienyl Ligands: Synthesis, Structure and Reactivity

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02362E, PaperZoe E Button, Jessica A Higgins, Marketa Suvova, Geoff Frederick Geoffrey Cloke, Mark Roe
The Th(IV) mixed-sandwich halide complexes Th(COTTIPS2)Cp*X (where COTTIPS2 = C8H6{1,4-SiiPr3}, X= Cl, I) have been synthesised, and structurally characterised. When Th(COTTIPS2)Cp*I is reduced in-situ in the presence of CO2, a...
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Stepped spin crossover in Fe(III) halogen substituted quinolylsalicylaldimine complexes

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01701C, PaperWasinee Phonsri, David James Harding, Phimphaka Harding, Keith S. Murray, Boujemaa Moubaraki, Ian Gass, John D Cashion, Harry Adams, Guy N L Jameson
The reaction of Fe(NCS)3 prepared in situ in MeOH with Hqsal-X (Hqsal-X = 5-X-N-quinolylsalicylaldimine) in CH2Cl2 yields the FeIII complexes, [Fe(qsal-X)2]NCS[middle dot]solvent (X = F 1; X = Cl, 2, Br,...
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Tripodal tris(hydroxypyridinone) ligands for immunoconjugate PET imaging with 89Zr4+: comparison with desferrioxamine-B

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02978J, PaperMichelle Ma, Levente K Meszaros, Brett Michael Paterson, David Berry, Maggie S Cooper, Yongmin Ma, Robert Hider, Philip J Blower
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Biomolecule-mediated CdS-TiO2-reduced graphene oxide ternary nanocomposites for efficient visible light driven photocatalysis

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02749C, PaperSoumen Dutta, Ramkrishna Sahoo, Chaiti Ray, Sougata Sarkar, Jayasmita Jana, Yuichi Negishi, T Pal
We report an environmental friendly synthetic strategy to fabricate reduced graphene oxide (rGO) based ternary nanocomposite where glutathione (GSH) acts both as a reducing agent for graphene oxide and sulfur...
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Efficient Removal of Perchlorate Ion from Water by Water-insoluble M2L4 Type Compound

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02900C, CommunicationMasaru Mochizuki, Tatsunari Inoue, Katsunori Yamanishi, Shiori Koike, Mitsuru Kondo, Liang Zhang, Hiromi Aoki
Reaction of CuSO4[middle dot]5H2O with 1,3-bis(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene (m-bbitrb) provides a new positively charged M2L4 type molecule, [SO4 [subset or is implied by] Cu2(m-bbitrb)4]SO4. This compound includes SO42- inside and outside the cationic cage. Despite this compound...
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Chiral Mononuclear Lanthanide Complexes and the Field-induced Single-ion Magnet Behaviour of Dy Analogue

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02889A, PaperShuang-Yan Lin, Chao Wang, Lang Zhao, Jianfeng Wu, Jinkui Tang
Three pairs of homochiral mononuclear lanthanide complexes, with general formula [LnH4LRRRRRR/SSSSSS(SCN)2](SCN)2[round bullet, filled]xCH3OH[round bullet, filled]yH2O (Ln = Dy (R/S-Dy1), Ho (R/S-Ho1) and Er (R/S-Er1)), have been obtained via self-assembly between chiral macrocyclic ligands and...
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A cheap and facile route to synthesize monodisperse magnetic nanocrystals and application as MRI agent

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02425G, Paperguixin yang, fei he, ruichan lv, shili gai, Ziyong Cheng, yunlu dai, piaoping yang
A facile solution-based thermal decomposition strategy, using very cheap polyisobutene succimide (PIBSI) and paraffin oil as surfactant and solvent, has been developed for the controllable synthesis of magnetic MnFe2O4 and...
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Luminescent 3D Interpenetrating Metal-Organic Framework for Highly Selective Sensing of Nitrobenzene

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02841D, CommunicationC M Nagaraja, Divyendu Singh
A three-dimensional (3D), luminescent, 5-fold interpenetrating metal-organic framework (MOF), [Zn2(fdc)2(bpee)2(H2O).2H2O] (1) exhibiting highly selective sensing of nitrobenzene (NB) via a fluorescence quenching mechanism has been demonstrated.
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Sulfonamide-Substituted Iron Phthalocyanine: Design, Solubility Range, Stability and Oxidation of Olefins

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02412E, CommunicationUmit Isci, Celal Caner, Yunus Zorlu, Ayse Gul Gurek, Fabienne Dumoulin, Vefa Ahsen
4-tert-butylbenzenesulfonamide was used as a substituent of tetra peripherally substituted Fe(II) phthalocyanine, taking in account several parameters crucial for the design of potential oxidation catalysts: solubility and stability. The resulting...
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Bifunctional 64Cu-labelled macrobicyclic cage amine isothiocyanates for immuno-positron emission tomography

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02983F, PaperBrett Michael Paterson, Gojko Buncic, Lachlan Eion McInnes, Peter Roselt, Carleen Cullinane, David Binns, Charmaine Jeffery, Roger Price, Rodney Hicks, Paul Stephen Donnelly
New macrobicyclic cage amine or "sarcophagine" (sar) bifunctional chelators have been synthesised that form copper complexes of exceptional in vivo stability and incorporate isothiocyanate (-NCS) functional groups for conjugation to...
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Synthesis and Properties of Greenish-Blue-Emitting Iridium Dendrimers with N-phenylcarbazole-Based Polyether Dendrons by A Post-Dendronization Route

Dalton Transactions - 22 October, 2014 - 21:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02815E, PaperYang Wang, Shumeng Wang, Shiyang Shao, Junqiao Ding, Lixiang Wang, Xiabin Jing, Fosong Wang
A series of solution processible greenish-blue-emitting Ir dendrimers with polyether dendrons that consist of N-phenylcarbazole (NPC) have been developed via a convenient post-dendronization method. It involves two steps: i) the...
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Studying the effects of Zr-doping in (Bi0.5Na0.5)TiO3 via diffraction and spectroscopy

Dalton Transactions - 22 October, 2014 - 21:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02520B, PaperPeter E. R. Blanchard, Samuel Liu, Brendan J. Kennedy, Chris D. Ling, Zhaoming Zhang, Maxim Avdeev, Ling-Yun Jang, Jyh-Fu Lee, Chih-Wen Pao, Jeng-Lung Chen
The phase transformation in the (Bi0.5Na0.5)Ti1-xZrxO3 are characterized using XRD and XANES.
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Electronic effects of substituents on the stability of the iridanaphthalene compound [Ir[upper bond 1 start]Cp*{[double bond, length as m-dash]C(OMe)CH[double bond, length as m-dash]C(o-C[upper bond 1 end]6H4)(Ph)}(PMe3)]PF6

Dalton Transactions - 22 October, 2014 - 21:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02744B, PaperM. Talavera, J. Bravo, J. Castro, S. Garcia-Fontan, J. M. Hermida-Ramon, S. Bolano
How do the substituents on the naphthalene skeleton affect the stability of the iridanaphthalene complex [Ir[upper bond 1 start]Cp*{[double bond, length as m-dash]C(OMe)CH[double bond, length as m-dash]C(o-C[upper bond 1 end]6H4)(Ph)}(PMe3)]PF6?
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