Royal Society of Chemistry

Metal-organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00395K, Review ArticleAdeel H. Chughtai, Nazir Ahmad, Hussein A. Younus, A. Laypkov, Francis Verpoort
Novel catalytic materials are highly demanded to perform a variety of catalytic organic reactions.
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Engineered biosynthesis of natural products in heterologous hosts

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C5CS00025D, Review ArticleYunzi Luo, Bing-Zhi Li, Duo Liu, Lu Zhang, Yan Chen, Bin Jia, Bo-Xuan Zeng, Huimin Zhao, Ying-Jin Yuan
Biosynthesis of natural products in heterologous hosts is improved significantly with new tools and strategies in synthetic biology.
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The excited state antiaromatic benzene ring: a molecular Mr Hyde?

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C5CS00057B, Review ArticleRaffaello Papadakis, Henrik Ottosson
Baird's rule tells that benzene is an antiaromatic "Mr Hyde" in its lowest excited states, explaining many photoreactions of benzene derivatives.
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The chemical biology of sirtuins

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00373J, Review ArticleBing Chen, Wenwen Zang, Juan Wang, Yajun Huang, Yanhua He, Lingling Yan, Jiajia Liu, Weiping Zheng
This article reviews the tremendous accomplishments achieved during the past few years in the field of chemical biology for the physiologically and therapeutically important sirtuin family of N[varepsilon]-acyl-lysine deacylase enzymes.
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Designing nanomaterials to maximize performance and minimize undesirable implications guided by the Principles of Green Chemistry

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00445K, Tutorial ReviewLeanne M. Gilbertson, Julie B. Zimmerman, Desiree L. Plata, James E. Hutchison, Paul T. Anastas
A sustainable material design framework is proposed that emphasizes the importance of establishing structure-property-function (SPF) and structure-property-hazard (SPH) relationships to guide the rational design of ENMs.
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Radical aryl migration reactions and synthetic applications

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C4CS00467A, Review ArticleZhi-Min Chen, Xiao-Ming Zhang, Yong-Qiang Tu
This review provides a comprehensive summary of radical aryl migration reactions, highlighting their mechanistic studies and synthetic applications.
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Peptide self-assembly triggered by metal ions

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C5CS00234F, Review ArticleRongfeng Zou, Qi Wang, Junchen Wu, Jingxian Wu, Carsten Schmuck, He Tian
This review summarizes the recent development of structures, functions, as well as strategies of a peptide self-assembly induced by metal ions.
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Flexible supercapacitors based on paper substrates: a new paradigm for low-cost energy storage

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C5CS00174A, Review ArticleYi-Zhou Zhang, Yang Wang, Tao Cheng, Wen-Yong Lai, Huan Pang, Wei Huang
This review introduces the background, design and applications of paper-based supercapacitors, highlighting their importance for low-cost flexible energy storage.
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Multi-platinum anti-cancer agents. Substitution-inert compounds for tumor selectivity and new targets

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C5CS00201J, Tutorial ReviewN. P. Farrell
Substitution-inert polynuclear platinum complexes are inherently dual-function anti-cancer agents combining extra and intra-cellular effects in one structural chemotype.
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The emergence of sulfoxides as efficient ligands in transition metal catalysis

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, 44,3834-3860
DOI: 10.1039/C4CS00524D, Review ArticleGellert Sipos, Emma E. Drinkel, Reto Dorta
This review describes the use of sulfoxides as ancillary ligands in transition metal catalysis.
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Vitamin B12 catalysed reactions

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, 44,3391-3404
DOI: 10.1039/C5CS00165J, Tutorial ReviewMaciej Giedyk, Katarzyna Goliszewska, Dorota Gryko
This tutorial review focuses on cobalamin as a natural, nontoxic, environmentally benign cobalt catalyst for synthetically useful organic reactions.
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The ADOR mechanism for the synthesis of new zeolites

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C5CS00045A, Review ArticlePavla Eliasova, Maksym Opanasenko, Paul S. Wheatley, Mariya Shamzhy, Michal Mazur, Petr Nachtigall, Wieslaw J. Roth, Russell E. Morris, Jiri Cejka
The ADOR method enables the synthesis of novel zeolitic structures via exploiting structural weakness present in some zeolites.
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To gel or not to gel: correlating molecular gelation with solvent parameters

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C5CS00136F, Review ArticleY. Lan, M. G. Corradini, R. G. Weiss, S. R. Raghavan, M. A. Rogers
Solvent parameters provide an understanding into the driving forces governing SAFiN formation aiding in the quest for a universal gelator.
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Sulfur imidations: access to sulfimides and sulfoximines

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, 44,3378-3390
DOI: 10.1039/C5CS00208G, Tutorial ReviewVincent Bizet, Christine M. M. Hendriks, Carsten Bolm
The overview describes sulfur imidation methods providing a practical "tool box" for synthetic chemists and discusses the advantages and disadvantages associated with the use of the various imidating agents.
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Heterogeneous and homogeneous catalysis for the hydrogenation of carboxylic acid derivatives: history, advances and future directions

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, 44,3808-3833
DOI: 10.1039/C5CS00038F, Review ArticleJames Pritchard, Georgy A. Filonenko, Robbert van Putten, Emiel J. M. Hensen, Evgeny A. Pidko
Recent progress in hydrogenation of carboxylic acid derivatives is described with a particular focus on the catalyst performance, composition and reaction mechanism.
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DYNAMERS: dynamic polymers as self-healing materials

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, 44,3786-3807
DOI: 10.1039/C5CS00194C, Review ArticleNabarun Roy, Bernd Bruchmann, Jean-Marie Lehn
An overview of recent advances made in the field of constitutional dynamic materials, in particular dynamic polymers, dynamers, displaying self-healing features.
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Synthesis of chemicals by metabolic engineering of microbes

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, 44,3760-3785
DOI: 10.1039/C5CS00159E, Review ArticleXinxiao Sun, Xiaolin Shen, Rachit Jain, Yuheng Lin, Jian Wang, Jing Sun, Jia Wang, Yajun Yan, Qipeng Yuan
This review provides a comprehensive outlook at the progress and developing trends in the biosynthesis of chemicals.
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Non-alternant non-benzenoid kekulenes: the birth of a new kekulene family

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C5CS00185D, Review ArticleHirokazu Miyoshi, Shunpei Nobusue, Akihiro Shimizu, Yoshito Tobe
Theoretical and experimental aspects of kekulene and its benzenoid, non-benzenoid and non-alternant type congeners are reviewed.
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Multiphotochromic molecular systems

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, 44,3719-3759
DOI: 10.1039/C5CS00137D, Review ArticleArnaud Fihey, Aurelie Perrier, Wesley R. Browne, Denis Jacquemin
We review molecular compounds encompassing several photochromic units with a focus on their functionalities.
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Design of Lewis-acid centres in zeolitic matrices for the conversion of renewables

Chem. Soc. Rev. - 26 May, 2015 - 12:54

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C5CS00028A, Review ArticlePierre Y. Dapsens, Cecilia Mondelli, Javier Perez-Ramirez
We review preparative approaches to introduce Lewis-acid centres in zeolites, underlining the structure-performance relationship and highlighting directions to design improved materials of practical relevance.
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