Royal Society of Chemistry

Label-free detection of Alzheimer's disease through the ADP3 peptoid recognizing the serum amyloid-beta42 peptide

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07037B, CommunicationZijian Zhao, Ling Zhu, Xiangli Bu, Huailei Ma, Shu Yang, Yanlian Yang, Zhiyuan Hu
Surface plasmon resonance imaging in combination with the ADP3 peptoid was used to identify Alzheimer's disease through detecting amyloid-beta42 in the serum.
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The inner filter effect of Cr(VI) on Tb-doped layered rare earth hydroxychlorides: new fluorescent adsorbents for the simple detection of Cr(VI)

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08543D, CommunicationHyunsub Kim, Byung-Il Lee, Song-Ho Byeon
The effective overlap of excitation bands of Tb-doped layered yttrium hydroxychlorides with absorption bands of Cr(VI) (both HCrO4- and CrO42- forms) constructs a new inner filter effect system resulting in fluorescence quenching.
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Application of a nucleophilic boryl complex in the frustrated Lewis pair: activation of H-H, B-H and C[double bond, length as m-dash]C bonds with B(C6F5)3 and boryl-borate lithium

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07658C, CommunicationJunhao Zheng, Yuwen Wang, Zhen Hua Li, Huadong Wang
The frustrated Lewis pair (FLP) comprised of boryl-borate lithium [pinBB(Ph)pin]Li and B(C6F5)3 can efficiently activate H2, HBpin and C2H4.
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Dual-responsive nanoparticles that aggregate under the simultaneous action of light and CO2

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08541H, CommunicationOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ji-Woong Lee, Rafal Klajn
Metallic nanoparticles co-functionalised with monolayers of UV- and CO2-sensitive ligands were prepared and shown to respond to these two types of stimuli reversibly and in an orthogonal fashion.
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The dual role of micelles as templates and reducing agents for the fabrication of catalytically active hollow silver nanospheres

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07872A, CommunicationManickam Sasidharan, Chenrayan Senthil, Vandana Kumari, Asim Bhaumik
A simple and efficient protocol for fabrication of colloidal hollow Ag nanospheres of size less than 30 nm using a triblock copolymer in the absence of any reducing agent is reported, which showed excellent catalytic activity in the Baeyer-Villiger oxidation reaction.
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Gold superacid-catalyzed preparation of benzo[c]thiophenes

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07989B, CommunicationWouter Debrouwer, Ruben A. J. Seigneur, Thomas S. A. Heugebaert, Christian V. Stevens
Gold(III) chloride catalyzes the cycloisomerization of dithioacetals to benzo[c]thiophenes by in situ formation of a gold superacid.
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A glucose-powered antimicrobial system using organic-inorganic assembled network materials

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07533A, CommunicationHuanxiang Yuan, Haotian Bai, Libing Liu, Fengting Lv, Shu Wang
A new glucose-driven photodynamic antimicrobial system was developed using organic-inorganic network materials encapsulating an enzyme cascade.
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Indium(III) chloride catalyzed highly diastereoselective domino synthesis of indenodithiepines and indenodithiocines

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07280D, CommunicationSengodagounder Muthusamy, Manickasamy Sivaguru, Eringathodi Suresh
An atom-economical diastereoselective synthesis of indenodithiepines and indenodithiocines has been developed via a domino reaction of propargylic alcohols and dithioacetals in the presence of InCl3 as a catalyst.
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Tertiary [small alpha]-diarylmethylamines derived from diarylketimines and organomagnesium reagents

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC06719C, CommunicationAlaric Desmarchelier, Pablo Ortiz, Syuzanna R. Harutyunyan
Organomagnesium reagents enable swift and versatile derivatisation of diarylimines to the corresponding [small alpha]-substituted diarylmethylamines in excellent yields, through fast and clean reactions.
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The role of MgB12H12 in the hydrogen desorption process of Mg(BH4)2

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC05266H, CommunicationYigang Yan, Arndt Remhof, Daniel Rentsch, Andreas Zuttel
Throughout the solid-state decomposition process of Mg(BH4)2, the MgB12H12 phase does not exist in the solid residues after decomposition.
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Facile synthesis of a pyrrole-fused dibenzo[a,e]pentalene and its application as a new extended, ladder-type fused aromatic system

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07721K, CommunicationCheng Li, Chunming Liu, Yan Li, Xiaozhang Zhu, Zhaohui Wang
A novel ladder-type pyrrole-fused dibenzo[a,e]pentalene is synthesized via double intermolecular Pd-catalyzed cascade crossover annulations.
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Formation of a quasi-solid structure by intercalated noble gas atoms in pores of CuI-MFU-4l metal-organic framework

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07554D, CommunicationOxana V. Magdysyuk, Dmytro Denysenko, Ingrid Weinrauch, Dirk Volkmer, Michael Hirscher, Robert E. Dinnebier
Ten crystallographically different positions for Xe and eight positions for Kr form a quasi-solid structures within the large-pore metal-organic framework CuI-MFU-4l.
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An exceptionally stable functionalized metal-organic framework for lithium storage

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07149B, CommunicationYichao Lin, Qiuju Zhang, Chongchong Zhao, Huailong Li, Chunlong Kong, Cai Shen, Liang Chen
A new functionalized MOF with remarkable thermal and chemical stability, and Li storage ability has been designed and synthesized.
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Beryllium bis(diazaborolyl): old neighbors finally shake hands

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08519A, CommunicationT. Arnold, H. Braunschweig, W. C. Ewing, T. Kramer, J. Mies, J. K. Schuster
The synthesis of a linear beryllium bis(diazaborolyl) compound featuring the first non-cluster bond between boron and beryllium has been achieved through the reaction of Yamashita's lithium diazaborolide and BeCl2.
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Structure orientation of hemin self-assembly layer determining the direct electron transfer reaction

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07719A, CommunicationGui-Xia Wang, Yue Zhou, Min Wang, Wen-Jing Bao, Kang Wang, Xing-Hua Xia
A strategy was proposed to control the hemin orientation via experimental models, which shows heme plane orientation dependent direct electron transfer and electrocatalysis.
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Multiple and configurable optical logic systems based on layered double hydroxides and chromophore assemblies

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08069F, CommunicationWenying Shi, Yi Fu, Zhixiong Li, Min Wei
Multiple and configurable fluorescence logic gates were fabricated through the self-assembly of layered double hydroxide nanosheets and three fluorescence chromophores.
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Oxidative Radical 1,2-Alkylarylation of Alkenes with -C(sp3)-H Bonds of Acetonitriles Involving 1,2-Aryl Migration

Chem. Commun. - 24 November, 2014 - 22:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC08902B, CommunicationYang Li, Bang Liu, Hai-Bing Li, Qiuan Wang, Jin-Heng Li
A novel metal-free oxidative 1,2-alkylarylation of unactivated alkenes with the -C(sp3)-H bonds of acetonitriles for the synthesis of 5-oxo-pentanenitriles is presented. In the presence of TBPB (tert-butyl peroxybenzoate), a variety...
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Ni-Catalyzed [small alpha]-Arylation of Esters and Amides with Phenol Derivatives

Chem. Commun. - 24 November, 2014 - 22:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC08426H, CommunicationEva Koch, Ryosuke Takise, Armido STUDER, Junichiro Yamaguchi, Kenichiro Itami
A nickel-catalyzed [small alpha]-arylation of esters and amides with phenol derivatives has been accomplished. In the presence of our unique nickel catalyst, prepared in situ from Ni(cod)2 and 3,4-bis(dicyclohexylphosphino)thiophene (dcypt), and...
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Isoselective 3,4-(co)Polymerization of Biorenewable Myrcene Using NSN-Ligated Rare-earth Metal Precursors: Approach to New Elastomer

Chem. Commun. - 24 November, 2014 - 22:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC08962F, CommunicationBo Liu, Lei Li, Guangping Sun, Dongtao Liu, Shihui Li, Dongmei Cui
Polymerization of biorenewable myrcene (MY) by using the cationic [small beta]-diimidosulfonate lutetium catalyst in high activity, afforded the unprecedented isotactic 3,4-polymyrcene (PMY) with a low Tg (-42 [degree]C), based on which,...
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Impact of a rigid backbone on the structure of an agostically-stabilised dialkylstannylene: isolation of an unusual bridged stannyl-stannylene

Chem. Commun. - 24 November, 2014 - 22:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08740B, CommunicationOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Keith Izod, Casey M. Dixon, Ross W. Harrington, Michael R. Probert
Tethering two phosphine-borane-stabilised carbanion centres in a single ligand reduces its capacity to form B-HE agostic-type interactions, and favours the formation of a stannyl-stannylene complex over two equivalents of the corresponding stannylene.
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