Royal Society of Chemistry

Formation of porous SnS nanoplate networks from solution and their application in hybrid solar cells

Chem. Commun. - 2 hours 52 min ago

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC03125G, CommunicationOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.T. Rath, L. Gury, I. Sanchez-Molina, L. Martinez, S. A. Haque
Herein, we present a facile solution-based route towards nanostructured, hybrid absorber layers based on tin mono-sulfide (SnS), an emerging, non-toxic absorber material for low-cost and large-scale PV applications.
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NIR Light Induced H2 Evolution by a Metal-free Photocatalyst

Chem. Commun. - 2 hours 52 min ago
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC02589C, CommunicationXinyuan Xia, Ning Deng, Guanwei Cui, Junfeng Xie, Xifeng Shi, Yingqiang Zhao, Qian Wang, Wen Wang, Bo Tang
NIR light induced H2 evolution was realized by metal-free photocatalysis for the first time. The considerable H2 production at 808 nm and large promotion to photocatalytic activity in both UV-Vis...
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FeCl3 Catalysed Synthesis of Substituted Indenones by Formal [2+2] Cycloaddition/Ring Opening Cascade of O-Keto-Cinnamates.

Chem. Commun. - 2 hours 52 min ago
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC03040D, CommunicationDATTATRAYA DETHE, Ganesh Murhade
A novel FeCl3 mediated formal [2+2] cycloaddition/ring opening cascade of o-keto-cinnamates was developed for the synthesis of indenones. The reaction tolerates a broad range of functional groups, including bromide, chloride,...
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Room-Temperature Acetylene Hydration by a Hg(II)-laced Metal-Organic Framework

Chem. Commun. - 2 hours 52 min ago
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC03943F, CommunicationKa-Kit Yee, Yan-Lung Wong, Meiqin Zha, Ramesh Adhikari, Mark T Tuominen, Jun He, Zhengtao Xu
We report a broadly useful, stepwise strategy for anchoring strongly Lewis acidic metal centers within porous frameworks-all by means of thiol-functionalized Zr(IV)-based metal-organic framework (MOF). First, the strong-binding thiol (-SH)...
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A step toward simplified detection of serum albumin on SDS-PAGE using an environment-sensitive flavone sensor

Chem. Commun. - 2 hours 52 min ago
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC03516C, CommunicationBin Liu, Yi Pang, Rachida Bouhenni, Ernest Duah, Sailaja Paruchuri, Lucas McDonald
In this study, we report a series of novel flavone-based sensors that exhibit superior fluorescence response when interacting with serum albumin in real serum samples and in acrylamide gel. The...
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Quantitative Determination of Fluoride in Pure Water using Luminescent Europium Complexes

Chem. Commun. - 2 hours 52 min ago
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC03428K, CommunicationStephen Butler
Two luminescent probes [Eu.L1-2]+ are reported for the rapid detection of fluoride in water. [Eu.L1-2]+ exhibit exceptional enhancements in Eu emission in the presence of fluoride, permitting its selective determination...
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Mg2+-assisted Low Temperature Reduction for Alloyed AuPd/C: Efficient Catalyst for Hydrogen Generation from Formic Acid at Room Temperature

Chem. Commun. - 2 hours 52 min ago
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC02604K, CommunicationShuang Wu, Fan Yang, Hao Wang, Rui Chen, Pingchuan Sun, Tiehong Chen
Mg2+-assisted low temperature reduction approach was applied to prepare alloyed AuPd/C nanocatalyst, which exhibited high activity in hydrogen generation from formic acid. At room temperature the initial turnover frequency (TOF)...
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A novel mechanochemical method for reconstructing the moisture-degraded HKUST-1

Chem. Commun. - 2 hours 52 min ago
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC02809D, CommunicationXuejiao Sun, Hao Li, Yujie Li, Feng Xu, Jing Xiao, Qibin Xia, Yingwei Li, Zhong Li
A novel mechanochemical method was proposed to reconstruct quickly moisture-degraded HKUST-1. The degraded HKUST-1 can be restored within minutes. The reconstructed samples were characterized, and confirmed to have 95% surface...
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Surfactant assisted formation of ruthenium nanochains under mild conditions and their catalytic CO oxidation activity

Chem. Commun. - 2 hours 52 min ago

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC09430A, CommunicationS. Sreedhala, C. P. Vinod
Spontaneous formation of ruthenium nanochains is accomplished in aqueous medium under mild conditions using a seed mediated protocol with cetyl trimethylammonium bromide (CTAB) as the capping agent.
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Nanoparticle-sulphur "inverse vulcanisation" polymer composites

Chem. Commun. - 2 hours 52 min ago
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC03419A, CommunicationJoseph Charles Bear, William John Peveler, Paul Mcnaughter, Ivan P Parkin, Paul O'Brien, Charles W Dunnill
Composites of sulphur polymers with nanoparticles such as PbS, with tunable optical properties are reported. A hydrothermal route incorporating pre-formed nanoparticles was used, and their physical and chemical properties evaluated...
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Amphiphilic tertiary amine N-oxides: a mediated radical emulsion polymerization with non-formation of alkoxyamine dormant chains

Chem. Commun. - 2 hours 52 min ago

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC02413G, CommunicationKaihua Shen, Debang Qi, Ying Li, Xinglin Zhao, Yang Li
Octadecylamine ethoxylate (EO = 5) N-oxides (AO-1805) were presented which are one kind of interfacial tertiary amine N-oxides that differs from TEMPO derivatives.
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Reactivity of Carbon Dioxide in Hydrofluoroethers: Facile Access to Cyclic Carbonates

Chem. Commun. - 2 hours 52 min ago
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC03896K, CommunicationBenoit Crousse, Thierry Milcent, marius mamone
The high solubility of CO2 in hydrofluoroethers led to various cyclic carbonates with excellent selectivities and yields. The fluorinated phase increased the amount of CO2 in contact with the reagents....
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Chemoenzymatic one-pot synthesis in aqueous medium: Combination of metal-catalysed allylic alcohol isomerisation-asymmetric bioamination

Chem. Commun. - 2 hours 52 min ago
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC03298A, CommunicationNicolas Rios Lombardia, Cristian Vidal, Maria Cocina, Francisco Moris, Joaquin Garcia-Alvarez, Javier Gonzalez-Sabin
The ruthenium-catalysed isomerisation of allylic alcohols was coupled, for the first time, with an asymmetric bioamination in a one-pot process in aqueous medium. In those cases involving proquiral ketones, the...
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Preparation of 3-Aryl-2-aminoindoles, 3-Allyl-3-amino-2-iminoindolines, and Tetrahydro-[1,4]diazepino[2,3-b]indoles from 3-Diazoindolin-2-imines

Chem. Commun. - 2 hours 52 min ago
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC03238E, CommunicationGuorong Sheng, Kai Huang, Shicong Ma, Jing Qian, Ping Lu, Yan-Guang Wang
The rhodium-catalyzed reactions of 3-diazoindolin-2-imines with N,N-dialkylanilines, N-allyl-N-alkylanilines, and N-propargyl-N-alkylanilines and 3-diazoindolin-2-imines furnished 3-aryl-2-aminoindoles, 3-allyl-3-amino-2-iminoindolines, and tetrahydro-[1,4]diazepino[2,3-b]indoles, respectively. 3-Diazoindolin-2-imines acted as precursors of [small alpha]-imino rhodium carbenes in these transformations.
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Influence of external magnetic field and magnetic-site dilution to the magnetic dynamics of one-dimensional Tb(III)-radical complex

Chem. Commun. - 2 hours 52 min ago
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC01889G, CommunicationLei-Lei Li, Shuang Liu, Han Li, Wei Shi, Peng Cheng
A new Tb(III)-radical chain complex was synthesized and characterized, which exhibits two separated relaxation processes. The influence of external magnetic field and magnetic-site dilution to the magnetic dynamics of one-dimensional...
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Reversible piezochromism in a molecular wine-rack

Chem. Commun. - 2 hours 52 min ago

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC02916C, CommunicationElena L. Harty, Alex R. Ha, Mark R. Warren, Amber L. Thompson, David R. Allan, Andrew L. Goodwin, Nicholas P. Funnell
Coupling of a 'wine-rack' lattice motif with molecular flexibility leads to a large piezochromic response in an organic material.
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Direct accessibility of mixed-metal (III/II) acid sites through the rational synthesis of porous metal carboxylates

Chem. Commun. - 2 hours 52 min ago

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC02550H, CommunicationS. Wongsakulphasatch, F. Nouar, J. Rodriguez, L. Scott, C. Le Guillouzer, T. Devic, P. Horcajada, J.-M. Greneche, P. L. Llewellyn, A. Vimont, G. Clet, M. Daturi, C. Serre
The scalable and environmentally-friendly synthesis of mixed-metal MOFs is presented.
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Virus-templated FRET platform for the rational design of ratiometric fluorescent nanosensors

Chem. Commun. - 2 hours 52 min ago

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC02866C, CommunicationLimin Chen, Yehong Wu, Yuan Lin, Qian Wang
Based on the precise nano-architecture of bacteriophage M13, a FRET-based fluorescent nanosensor has been formulated for the ratiometric sensing of intracellular pH.
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Enantioselective synthesis of 3-fluoro-3-allyl-oxindoles via phosphine-catalyzed asymmetric [gamma]-addition of 3-fluoro-oxindoles to 2,3-butadienoates

Chem. Commun. - 2 hours 52 min ago

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC03289J, CommunicationTianli Wang, Ding Long Hoon, Yixin Lu
The first phosphine-catalyzed enantioselective [gamma]-addition of 3-fluoro-oxindoles to 2,3-butadienoates has been developed.
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Reversible thermo-sensitivity induced from varying the hydrogen bonding between the side residues of rationally designed polypeptides

Chem. Commun. - 2 hours 52 min ago

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC03017J, CommunicationHong Liu, Yan Xiao, Heng Xu, Yebin Guan, Jun Zhang, Meidong Lang
Balancing the ratio of the hydrogen bond acceptor/donor in the side residues of poly(L-glutamate) derivatives endows the copolypeptide obtained with reversible thermosensitivity.
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