Royal Society of Chemistry

Material considerations and locomotive capability in catalytic tubular microengines

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM16813H, HighlightGaoshan Huang, Joseph Wang, Yongfeng Mei
Tubular microengines harvesting chemical energy from catalytic reactions realize controllable autonomous locomotion at low Reynolds number.
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Asymmetric and symmetric PCR of gold nanoparticles: A pathway to scaled-up self-assembly with tunable chirality

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM15800K, PaperYuan Zhao, Liguang Xu, Hua Kuang, Libing Wang, Chuanlai Xu
In this work we used a polymerase chain reaction (PCR) to produce complex superstructures from heterogeneously-sized gold nanoparticles. By controlling the number of PCR cycles and primer density, two distinct superstructures were assembled at asymmetric and symmetric PCR.
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Functionalized polyacetylenes with strong luminescence: "turn-on" fluorescent detection of cyanide based on the dissolution of gold nanoparticles and its application in real samples

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM15516H, PaperXiaoding Lou, Qi Zeng, Yi Zhang, Zhaomin Wan, Jingui Qin, Zhen Li
By dissolution of Au NPs, new polyacetylene-functionalized Au-NPs were successfully developed as "turn-on" fluorescent probes for the detection of cyanide sensitively and selectively.
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Improved thin film morphology and bulk-heterojunction solar cell performance through systematic tuning of the surface energy of conjugated polymers

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM15517F, PaperYing Sun, Shang-Chieh Chien, Hin-Lap Yip, Kung-Shih Chen, Yong Zhang, Joshua A. Davies, Fang-Chung Chen, Baoping Lin, Alex K.-Y. Jen
We have shown that significantly improved thin film morphology and bulk-heterojunction solar cell performance can be achieved by systematically tuning the surface energy of conjugated polymer donors through side-chain functionalization.
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Comparison of symmetric and asymmetric bipolar type high triplet energy host materials for deep blue phosphorescent organic light-emitting diodes

J. Material Chem. - 1 hour 31 min ago
J. Mater. Chem., 2012, Accepted Manuscript
DOI: 10.1039/C2JM30742A, PaperSoon Ok Jeon, Jun Yeob Lee
Symmetric and asymmetric bipolar host materials for deep blue phosphorescent organic light-emitting diodes were developed and the chemical structure of the host materials was correlated with the device performances. The...
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A binder-free process for making all-plastic substrate flexible dye-sensitized solar cells having a gel electrolyte

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM15360B, PaperLi-Chieh Chen, Jyh-Ming Ting, Yuh-Lang Lee, Min-Hsiung Hon
Binder-free electrophoretic deposition (EPD) and mechanical compression were employed to fabricate TiO2 photoanodes for use in all-plastic substrate flexible dye-sensitized solar cells having a gel electrolyte.
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A novel conjugated polyfluorene: synthesis, characterization and application in label-free ECL immunoassays for biomarker detection

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM15481A, PaperMei Yan, Weiqiang Gao, Shenguang Ge, Lei Ge, Chengchao Chu, Jinghua Yu, Xianrang Song, Shengnan Hou
A novel amino-functionalized polyfluorene derivative was designed and synthesized. An ECL label-free immunosensor was prepared by chemical modification of a polyfluorene derivative on an ITO glass electrode.
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Enhanced n-type thermopower in distortion-free LiMn2O4

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM16297K, CommunicationTaylor D. Sparks, Aleksander Gurlo, David R. Clarke
Enhanced n-type thermopower of -73 [small mu ]V K-1 is reported for Jahn-Teller distortion free LiMn2O4 due to an increased electronic degeneracy ratio.
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Solvent and polymer matrix effects on TIPS-pentacene/polymer blend organic field-effect transistors

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM16487F, PaperDo Kyung Hwang, Canek Fuentes-Hernandez, John D. Berrigan, Yunnan Fang, Jungbae Kim, William J. Potscavage, Hyeunseok Cheun, Kenneth H. Sandhage, Bernard Kippelen
The effects of solvent and polymer matrix selection on the phase segregation behavior of TIPS-pentacene/polymer blend films, and on the resulting device performance, are evaluated.
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Topological loading of Cu(I) catalysts onto crystalline cellulose nanofibrils for the Huisgen click reaction

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM15661J, PaperHirotaka Koga, Akihiro Azetsu, Eriko Tokunaga, Tsuguyuki Saito, Akira Isogai, Takuya Kitaoka
Highly dispersed and exposed Cu(I) catalysts were topologically loaded over the crystalline surfaces of cellulose nanofibrils for the Huisgen reaction.
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A novel approach to electrospinning of pristine and aligned MEH-PPV using binary solvents

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM15970H, PaperWei Zhong, Fan Li, Lie Chen, Yiwang Chen, Yen Wei
Continuous electrospinning of pristine and aligned MEH-PPV in binary solvents without adding a polymer or a surfactant has been demonstrated. Polarization anisotropy spectra of aligned electrospun fibers indicated preferential alignment of MEH-PPV along the electrospun fiber axis. Electrospun fibers of MEH-PPV/PCL had higher polarization anisotropy than aligned pristine MEH-PPV at emission peak.
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Effects of direct solvent exposure on the nanoscale morphologies and electrical characteristics of PCBM-based transistors and photovoltaics

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM15260F, PaperSooji Nam, Jaeyoung Jang, Hyojung Cha, Jihun Hwang, Tae Kyu An, Seonuk Park, Chan Eon Park
The optimal phase separation in the P3HT/PCBM films was obtained simply by direct exposure of solvents for a few seconds.
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Iron supported C@Fe3O4 nanotube array: a new type of 3D anode with low-cost for high performance lithium-ion batteries

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM15955D, PaperKeyu Xie, Zhouguang Lu, Haitao Huang, Wei Lu, Yanqing Lai, Jie Li, Limin Zhou, Yexiang Liu
Iron supported C@Fe3O4 nanotube array is used as a novel type of 3D anode for lithium-ion batteries, showing attractive electrochemical performance.
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A highly efficient dye-sensitized solar cell with a platinum nanoflowers counter electrode

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM14623A, PaperTien-Lin Hsieh, Hsin-Wei Chen, Chung-Wei Kung, Chun-Chieh Wang, R. Vittal, Kuo-Chuan Ho
Platinum nanoflowers were synthesized by pulse reversal electrodeposition on conducting glass and applied to the counter electrode of a dye-sensitized solar cell to achieve a high efficiency of 8.13%.
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Electrodeposition of luminescent composite metal coatings containing rare-earth phosphor particles

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM13925A, PaperMurugan Ganapathi, Svetlana V. Eliseeva, Neil R. Brooks, Dimitri Soccol, Jan Fransaer, Koen Binnemans
Luminescent metal coatings incorporating red, yellow, green or blue rare-earth phosphor particles were prepared by electrodeposition from a non-aqueous electrolyte.
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Multi-addressable photochromic terarylene containing benzo[b]thiophene-1,1-dioxide unit as ethene bridge: multifunctional molecular logic gates on unimolecular platform

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM14973G, PaperShangjun Chen, Yuheng Yang, Yue Wu, He Tian, Weihong Zhu
A novel photochromic terarylene BTO allows access to multiple states triggered by metal ions, protons and light, specifically for constructing multifunctional molecular logic gates on the unimolecular platform.
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Sulfated graphene as an efficient solid catalyst for acid-catalyzed liquid reactions

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM16608A, PaperFujian Liu, Jing Sun, Longfeng Zhu, Xiangju Meng, Chenze Qi, Feng-Shou Xiao
Compared with conventional SO3H-functionalized ordered mesoporous carbons and silicas, G-SO3H is a highly active, very stable, and excellently recyclable catalyst, which may be attributed to its unique graphene structure and there is almost no limitation of mass transfer for acid-catalyzed liquid reactions.
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Synthesis of chitosan-coated near-infrared layered double hydroxide nanoparticles for in vivo optical imaging

J. Material Chem. - 1 hour 31 min ago

J. Mater. Chem., 2012, Advance Article
DOI: 10.1039/C2JM16447G, PaperPei-Ru Wei, Shih-Hsun Cheng, Wei-Neng Liao, Kun-Che Kao, Ching-Feng Weng, Chia-Hung Lee
The chitosan-coated layered double hydroxide nanoparticles (LDHs)-indocyanine green samples have a high potential for the development of both organ-specific drug delivery systems and in vivo contrast agents for clinical cancer diagnosis and chemotherapy. LDHs coated with different amounts of chitosan showed a specific accumulation of nanoparticles in different target organs when injected intravenously.
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Discovery and Evaluation of a Single Source Selenium Sulfide Precursor for the Synthesis of Alloy PbSxSe1-x Nanocrystals

J. Material Chem. - 1 hour 31 min ago
J. Mater. Chem., 2012, Accepted Manuscript
DOI: 10.1039/C2JM30408B, PaperGeoffrey Ozin, Jordan William Thomson, Xiang Wang, Laura Hoch, Daniel O Faulkner, Srebri Petrov
In this article, we evaluate the use of a novel single source SemSn precursor for the synthesis of alloy PbSxSe1-x nanocrystals using oleylamine as stabilizing ligand, reagent and solvent. The...
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Arrays of Ultrafine CuS Nanoneedles Supported on CNT Backbone for Application in Supercapacitors

J. Material Chem. - 1 hour 31 min ago
J. Mater. Chem., 2012, Accepted Manuscript
DOI: 10.1039/C2JM30437F, PaperXiong Wen (David) Lou
Supercapacitors for their very high power density are attracting increasing interest in the past few years as a complementary power source to lithium-ion batteries. Therefore, there is an urgent need...
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