NMR Properties of lithium

Common reference compound: LiCl/D2O, 9.7 mol kg-1 for both 6Li and 7Li.

Table of NMR-active nucleus propeties of lithium
  Isotope 1 Isotope 2 Isotope 3
Isotope 6Li 7Li
Natural abundance /% 7.59 92.41
Spin (I) 1 3/2
Frequency relative to 1H = 100 (MHz) 14.716086 38.863797
Receptivity, DP, relative to 1H = 1.00 0.000645 0.271
Receptivity, DC, relative to 13C = 1.00 3.79 1590
Magnetogyric ratio, γ (107 rad T-1 s-1) 3.9371709 10.3977013
Magnetic moment, μ (μN) 1.1625637 4.20407505
Nuclear quadrupole moment, Q/millibarn -0.808 -40.1
Line width factor, 1056l (m4) 0.033 21

References

  1. R.K. Harris in Encyclopedia of Nuclear Magnetic Resonance, D.M. Granty and R.K. Harris, (eds.), vol. 5, John Wiley & Sons, Chichester, UK, 1996. I am grateful to Professor Robin Harris (University of Durham, UK) who provided much of the NMR data, which are copyright 1996 IUPAC, adapted from his contribution contained within this reference.
  2. J. Mason in Multinuclear NMR, Plenum Press, New York, USA, 1987. Where given, data for certain radioactive nuclei are from this reference.
  3. P. Pyykkö, Mol. Phys., 2008, 106, 1965-1974.
  4. P. Pyykkö, Mol. Phys., 2001, 99, 1617-1629.
  5. P. Pyykkö, Z. Naturforsch., 1992, 47a, 189. I am grateful to Professor Pekka Pyykkö (University of Helsinki, Finland) who provided the nuclear quadrupole moment data in this and the following two references.
  6. D.R. Lide, (ed.), CRC Handbook of Chemistry and Physics 1999-2000 : A Ready-Reference Book of Chemical and Physical Data (CRC Handbook of Chemistry and Physics, CRC Press, Boca Raton, Florida, USA, 79th edition, 1998.
  7. P. Pyykkö, personal communication, 1998, 204, 2008, 2010.
  8. The isotopic abundances are extracted from the naturally occurring isotopes section within WebElements.

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lithium atomic number