Krypton: the essentials

Krypton is present in the air at about 1 ppm. The atmosphere of Mars contains a little (about 0.3 ppm) of krypton. It is characterised by its brilliant green and orange spectral lines. The spectral lines of krypton are easily produced and some are very sharp. In 1960 it was internationally agreed that the fundamental unit of length, the metre, should be defined as 1 m = 1,650,763.73 wavelengths (in vacuo) of the orange-red line of Kr-33.

Under normal conditions krypton is colourless, odourless, fairly expensive gas. Solid krypton is a white crystalline substance with a face-centered cubic structure which is common to all the "rare gases". Krypton difluoride, KrF2, has been prepared in gram quantities and can be made by several methods.

krypton
Image adapted with permission from Prof James Marshall's (U. North Texas, USA) Walking Tour of the elements CD.

Krypton: historical information

Krypton was discovered by Sir William Ramsay, Morris W. Travers in 1898 at Great Britain. Origin of name: from the Greek word "kryptos" meaning "hidden".

Krypton was discovered in 1898 by Sir William Ramsay and his student Morris Travers in the residue left after liquid air had nearly boiled away. Krypton was left in the residue after boiling away water, oxygen, nitrogen, helium, and argon from the sample of air. Krypton is present in the air at about 1 ppm. Neon was discovered by a similar procedure by the same workers just a few weeks later.

Krypton around us Read more »

Krypton has no biological role.

Krypton is present in the air to the extent of about 1 ppm. The atmosphere of Mars contains a little krypton (about 0.3 ppm).

Abundances for cobalt in a number of different environments. More abundance data »
Location ppb by weight ppb by atoms Links
Universe 40 0.6 Chemical elements abundance by weight in the universe on a miniature periodic table spark table
Crustal rocks 0.15 0.04 Chemical elements abundance by weight in the earth's crust on a miniature periodic table spark table
Human (no data) ppb by weight (no data) atoms relative to C = 1000000 Chemical elements abundance by weight in humans on a miniature periodic table spark table

Physical properties Read more »

Heat properties Read more »

Crystal structure Read more »

The solid state structure of krypton is: ccp (cubic close-packed).

Krypton: orbital properties Read more »

Krypton atoms have 36 electrons and the shell structure is 2.8.18.8. The ground state electronic configuration of neutral Krypton is [Ar].3d10.4s2.4p6 and the term symbol of Krypton is 1S0.

Isolation

Isolation: krypton is present to a small extent (about 1 ppm by volume) in the atmosphere and is obtained as a byproduct from the liquefaction and separation of air. This would not normally be carried out in the laboratory and krypton is available commercially in cylinders at high pressure.

Krypton isotopes Read more »

Krypton isotopes are used in various medical and scientific applications. Kr-82 is used for the production of Rb-81/Kr-81m generators. Many of the stable isotopes of Krypton are used in the study of the pulmonary system. Kr-78 can be used for the production of Br-75 although production of Br-75 via Se-76 is more common. Kr-86 has been used to define the standard measure of length: 1 meter is exactly 1,650,763.73 wavelengths of this isotope.

Table. Stables isotopes of cobalt.
Isotope Mass
/Da
Natural
abund.
(atom %)
Nuclear
spin (I)
Nuclear
magnetic
moment (μ/μN)
78Kr 77.920396 (9) 0.35 (1) 0
80Kr 79.916380 (9) 2.28 (6) 0
82Kr 81.913482 (6) 11.58 (14) 0
83Kr 82.914135 (4) 11.49 (6) 9/2 -0.970669
84Kr 83.911507 (4) 57.00 (4) 0
86Kr 85.910616 (5) 17.30 (22) 0

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