Iodine: the essentials
Iodine is a bluish-black, lustrous solid. It volatilises at ambient temperatures into a pretty blue-violet gas with an irritating odour.
It forms compounds with most elements, but is less reactive than the other halogens, which displace it from iodides. Iodine exhibits some metallic-like properties. It dissolves readily in chloroform, carbon tetrachloride, or carbon disulphide to form beautiful purple solutions. It is only slightly soluble in water. Iodine compounds are important in organic chemistry and very useful in medicine and photography. Lack of iodine is the cause of goitre (Derbyshire neck). The deep blue colour with starch solution is characteristic of the free element. It is assimilated by seaweeds from which it may be recovered, and is found in Chilean saltpetre, caliche, old salt brines, and salt wells.
Iodine: historical information
Iodine was discovered by Barnard Courtois in 1811. He isolated iodine from treating seaweed ash with sulphuric acid (H2SO4) while recovering sodium and potassium compounds.
Iodine: physical properties
Iodine: orbital properties
Isolation: iodine is available commercially so it is not normally necessary to make it in the laboratory. Iodine occurs in seawater but in much smaller quantities than chloride or bromide. As for bromine, with suitable sources of brine, it is recovered commercially through the treatment of brine with chlorine gas and flushing through with air. In this treatment, iodide is oxidized to iodine by the chlorine gas.
2I- + Cl2 → 2Cl- + I2
Small amounts of iodine can be made through the reaction of solid sodium iodide, NaI, with concentrated sulphuric acid, H2SO4. The first stage is formation of HI, which is a gas, but under the reaction conditions some of the HI is oxidized by further H2SO4 to form iodine and sulphur dioxide.
NaI (s) + H2SO4 (l) → HI (g) + NaHSO4 (s)
2HI (g) + H2SO4 (l) → I2 (g) + SO2 (g) + 2H2O (l)
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