Germanium: the essentials

Germanium is a gray-white semi-metal, and in its pure state is crystalline and brittle, retaining its lustre in air at room temperature. It is a very important semiconductor material. Zone-refining techniques have led to production of crystalline germanium for semiconductor use with an impurity of only one part in 10-10.

Certain germanium compounds have a low mammalian toxicity, but a clear activity against certain bacteria, which makes them of interest as chemotherapeutic agents.

germanium

Germanium: historical information

Germanium was discovered by Clemens Winkler in 1886 at Germany. Origin of name: from the Latin word "Germania" meaning "Germany".

Germanium was an element whose existence was predicted by Mendeleev in 1871. He predicted that the then unknown element germanium should resemble silicon in its properties. He suggested therefore the name ekasilicon (symbol Es). His predictions for the properties of germanium are remarkably close to the reality. Germanium was discovered in a mineral called argyrodite by Clemens Alexander Winkler in 1886.

Germanium around us Read more »

Germanium has no biological role but is said to stimulate the metabolism.

Germanium is not found as the free element in nature. Germanium is found in germanite, argyrodite, and some zinc ores. It is also present in coal and its presence in coal insures reserves for many years.

Abundances for cobalt in a number of different environments. More abundance data »
Location ppb by weight ppb by atoms Links
Universe 200 3 Chemical elements abundance by weight in the universe on a miniature periodic table spark table
Crustal rocks 1400 390 Chemical elements abundance by weight in the earth's crust on a miniature periodic table spark table
Human (no data) ppb by weight (no data) atoms relative to C = 1000000 Chemical elements abundance by weight in humans on a miniature periodic table spark table

Physical properties Read more »

Heat properties Read more »

Crystal structure Read more »

The solid state structure of germanium is: ccp (cubic close-packed).

Germanium: orbital properties Read more »

Germanium atoms have 32 electrons and the shell structure is 2.8.18.4. The ground state electronic configuration of neutral Germanium is [Ar].3d10.4s2.4p2 and the term symbol of Germanium is 3P0.

Isolation

Isolation: there is normally no need to make germanium in the laboratory as it is readily available commercially. Germanium is available through the treatment of germanium dioxide, GeO2, with carbon or hydrogen. The extraction of germanium from flue dust is complex because of the difficulty in separating it from zinc, which is also present.

GeO2 + 2C → Ge + 2CO

GeO2 + 2H2 → Ge + 2H2O

Very pure germanium can be made by the reaction of GeCl4 with hydrogen.

GeCl4 + 2H2 → Ge + 4HCl

Germanium isotopes Read more »

Germanium isotopes are mainly used for the production of medical As and Se radioisotopes. Ge-74 is used for the production of As-74, Ge-76 for the production of As-77, Ge-74 for the production of As-73 and Ge-72 for As-72. Ge-70, Ge-72 and Ge-74 can all be used for the production of the medical radioisotope Se-73, although the most common production route is via natural As (As-75). Natural GeF4 is used in the semiconductor pre-amorphisation implant process. The use of Ge-72, in the form of GeF4, improves this process and reduces contamination.

Table. Stables isotopes of cobalt.
Isotope Mass
/Da
Natural
abund.
(atom %)
Nuclear
spin (I)
Nuclear
magnetic
moment (μ/μN)
70Ge 69.9242497 (16) 20.84 (87) 0
72Ge 71.9220789 (16) 27.54 (34) 0
73Ge 72.9234626 (16) 7.73 (5) 9/2 -0.8794669
74Ge 73.9211774 (15) 36.28 (73) 0
76Ge 75.9214016 (17) 7.61 (38) 0

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