Vanadium: vanadium trichloride

vanadium trichloride is known by the following synonyms:

  • vanadium trichloride
  • vanadium(III) chloride
  • vanadium chloride

The oxidation number of vanadium in vanadium trichloride is 3.

  • Formula: VCl3
  • Hill system formula: Cl3V1
  • CAS registry number: [7718-98-1]
  • Formula weight: 157.3
  • Class: chloride
  • Colour: red-violet
  • Appearance: crystalline solid
  • Melting point: 400°C (disproportionates to VCl2 + VCl4)
  • Boiling point:
  • Density: 3000 kg m-3

Synthesis

Not available

Solid state structure

  • Geometry of vanadium: 6 coordinate: octahedral
  • Prototypical structure:

Crystal structure of vanadium trichloride

Element analysis

Element percentages in vanadium trichloride
Element %
Cl 67.61
V 32.39

Isotope pattern for VCl3

THe chart below shows the calculated isotope pattern for the formula VCl3 with the most intense ion set to 100%.

Suppliers

Coming soon...

References

The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

  • R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
  • N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
  • F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
  • A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
  • R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
  • A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
  • A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
  • J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
  • D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
  • J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
  • J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.

WebElements Shop

You can buy periodic table posters, mugs, T-shirts, fridge magnets, games, molecular models, and more at the WebElements shop