Technetium compounds: technetium tetrachloride

technetium symbol icon

The technetium in technetium tetrachloride formally is in the oxidation state 4.

Crystal structure of technetium tetrachloride

Technetium tetrachloride

  • Formula as often written: TcCl4
  • Hill system formula: Cl4Tc1
  • CAS registry number: [14215-13-5]
  • Formula weight: 239.718
  • Class: chloride


  • technetium tetrachloride
  • technetium(IV) chloride
  • technetium chloride

Physical properties

  • Colour: red
  • Appearance:
  • Melting point:
  • Boiling point: 300°C
  • Density:


Coming soon...

Element analysis

Element percentages for the elements in technetium tetrachloride
Element %
Cl 59.16
Tc 40.84


Not available

Solid state structure

  • Geometry of technetium:
  • Prototypical structure:

Crystal structure of technetium tetrachloride

Isotope pattern

What follows is the calculated isotope pattern for the TcCl4 unit with the most intense ion set to 100%.

Formula: Tc1Cl4

mass  %
239  78.2 _______________________________________
240 0.0
241 100.0 __________________________________________________
242 0.0
243 48.0 ________________________
244 0.0
245 10.2 _____
246 0.0
247 0.8


The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

  • R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
  • N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
  • F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
  • A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
  • R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
  • A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
  • A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
  • J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
  • D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
  • J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
  • J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.

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