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Samarium compounds: disamarium trisulphide
The samarium in disamarium trisulphide formally is in the oxidation state 3.
Disamarium trisulphide
- Formula as often written: Sm2S3
- Hill system formula: S3Sm2
- CAS registry number: [12067-22-0]
- Formula weight: 396.918
- Class: sulphide
Synonyms
- disamarium trisulphide
- samarium(III) sulphide
- disamarium trisulfide
- samarium sulfide
- samarium sulphide
- samarium(III) sulfide
Physical properties
- Colour: grey-brown
- Appearance: crystalline solid
- Melting point: 1720°C
- Boiling point:
- Density: 5900 kg m-3
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Element analysis
Element percentages for the elements in disamarium trisulphide
| Element |
% |
| S |
24.24 |
| Sm |
75.76 |
Synthesis
Not available
Isotope pattern
What follows is the calculated isotope pattern for the Sm2S3 unit with the most intense ion set to 100%.
Formula: Sm2S3
mass %
384 0.6 385 0.0 386 0.1 387 5.9 ___ 388 4.6 __ 389 6.3 ___ 390 18.0 _________ 391 22.7 ___________ 392 47.8 ________________________ 393 38.0 ___________________ 394 38.6 ___________________ 395 69.4 ___________________________________ 396 48.0 ________________________ 397 100.0 __________________________________________________ 398 65.8 _________________________________ 399 53.7 ___________________________ 400 75.8 ______________________________________ 401 7.6 ____ 402 86.5 ___________________________________________ 403 2.2 _ 404 43.5 ______________________ 405 0.9 406 4.9 __ 407 0.1 408 0.2 409 0.0 410 0.0
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.
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