Ruthenium compounds: tris(2,2'-bipyridyl)ruthenium dichloride

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The ruthenium in tris(2,2'-bipyridyl)ruthenium dichloride formally is in the oxidation state 2.

Tris(2,2'-bipyridyl)ruthenium dichloride

  • Formula as often written: [Ru(C10H8N2)3]Cl2.6H2O
  • Hill system formula: C30Cl2H36N6O6Ru1
  • CAS registry number: [50525-27-4]
  • Formula weight: 748.619
  • Class: complex

Synonyms

  • tris(2,2'-bipyridyl)ruthenium dichloride
  • tris(2,2'-dipyridyl)ruthenium(II) chloride

Physical properties

  • Colour:
  • Appearance: crystalline solid
  • Melting point:
  • Boiling point:
  • Density:

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Element analysis

Element percentages for the elements in tris(2,2'-bipyridyl)ruthenium dichloride
Element %
C 48.13
Cl 9.47
H 4.85
N 11.23
O 12.82
Ru 13.50

Synthesis

Not available

Isotope pattern

What follows is the calculated isotope pattern for the [Ru(C10H8N2)3]Cl2.6H2O unit with the most intense ion set to 100%.

Formula: Ru1C30H36N6Cl2O6

mass  %
742  11.0 ______
743 4.0 __
744 11.6 ______
745 29.4 _______________
746 38.6 ___________________
747 62.5 _______________________________
748 100.0 __________________________________________________
749 57.2 _____________________________
750 95.5 ________________________________________________
751 35.3 __________________
752 38.0 ___________________
753 12.2 ______
754 6.3 ___
755 1.7 _
756 0.3
757 0.0

References

The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

  • R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
  • N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
  • F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
  • A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
  • R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
  • A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
  • A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
  • J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
  • D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
  • J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
  • J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.

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ruthenium atomic number