|
|
Rhodium compounds: hexarhodium hexadecacarbonyl
The rhodium in hexarhodium hexadecacarbonyl formally is in the oxidation state 0.
Hexarhodium hexadecacarbonyl
- Formula as often written: Rh6(CO)16
- Hill system formula: C16O16Rh6
- CAS registry number: [28407-51-4]
- Formula weight: 1065.595
- Class: carbonyl
complex
organometallic
Synonyms
- hexarhodium hexadecacarbonyl
- rhodium(O) carbonyl
- rhodium carbonyl
- rhodium hexadecacarbonyl
Physical properties
- Colour: violet-brown to black
- Appearance: solid
- Melting point: 242°C
- Boiling point:
- Density:
Suppliers
Element analysis
Element percentages for the elements in hexarhodium hexadecacarbonyl
| Element |
% |
| C |
18.03 |
| O |
24.02 |
| Rh |
57.94 |
Synthesis
Not available
Isotope pattern
What follows is the calculated isotope pattern for the Rh6(CO)16 unit with the most intense ion set to 100%.
Formula: Rh6C16O16
mass %
1066 100.0 __________________________________________________ 1067 18.4 _________ 1068 4.8 __ 1069 0.7 1070 0.1
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.
|
|