Platinum compounds: platinum tetrafluoride

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The platinum in platinum tetrafluoride formally is in the oxidation state 4.

Crystal structure of platinum tetrafluoride

Platinum tetrafluoride

  • Formula as often written: PtF4
  • Hill system formula: F4Pt1
  • CAS registry number: [13455-15-7]
  • Formula weight: 271.072
  • Class: fluoride

Synonyms

  • platinum tetrafluoride
  • platinum(IV) fluoride
  • platinum fluoride

Physical properties

  • Colour: yellow-brown or red
  • Appearance: crystalline solid
  • Melting point: 600°C
  • Boiling point:
  • Density:

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Element analysis

Element percentages for the elements in platinum tetrafluoride
Element %
F 28.03
Pt 71.97

Synthesis

Not available

Solid state structure

  • Geometry of platinum:
  • Prototypical structure:

Crystal structure of platinum tetrafluoride

Isotope pattern

What follows is the calculated isotope pattern for the PtF4 unit with the most intense ion set to 100%.

Formula: Pt1F4

mass  %
266   0.0 
267 0.0
268 2.3 _
269 0.0
270 97.3 _________________________________________________
271 100.0 __________________________________________________
272 74.9 _____________________________________
273 0.0
274 21.3 ___________

References

The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

  • R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
  • N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
  • F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
  • A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
  • R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
  • A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
  • A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
  • J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
  • D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
  • J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
  • J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.

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