Phosphorus compounds: tetraphosphorus triselenide

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The phosphorus in tetraphosphorus triselenide formally is in the oxidation state .

Crystal structure of tetraphosphorus triselenide

Tetraphosphorus triselenide

  • Formula as often written: P4Se3
  • Hill system formula: P4Se3
  • CAS registry number: [1314-86-9]
  • Formula weight: 360.775
  • Class: selenide

Synonyms

  • tetraphosphorus triselenide
  • phosphorus selenide
  • phosphorus triselenide

Physical properties

  • Colour: orange-red
  • Appearance: crystalline solid
  • Melting point: 245°C
  • Boiling point: 380°C
  • Density: 1310 kg m-3

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Element analysis

Element percentages for the elements in tetraphosphorus triselenide
Element %
P 34.34
Se 65.66

Synthesis

Not available

Solid state structure

  • Geometry of phosphorus: 3 coordinate: pyramidal
  • Prototypical structure:

Crystal structure of tetraphosphorus triselenide

Isotope pattern

What follows is the calculated isotope pattern for the P4Se3 unit with the most intense ion set to 100%.

Formula: P4Se3

mass  %
348   0.0 
349 0.0
350 0.1
351 0.0
352 0.9
353 0.1
354 4.5 __
355 0.6
356 15.8 ________
357 1.6 _
358 40.3 ____________________
359 2.7 _
360 76.2 ______________________________________
361 3.1 __
362 100.0 __________________________________________________
363 1.0
364 88.2 ____________________________________________
365 0.1
366 34.5 _________________
367 0.0
368 5.9 ___
369 0.0
370 0.4

References

The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

  • R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
  • N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
  • F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
  • A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
  • R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
  • A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
  • A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
  • J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
  • D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
  • J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
  • J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.

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