Phosphorus compounds: phosphorus trichloride

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The phosphorus in phosphorus trichloride formally is in the oxidation state 3.

Crystal structure of phosphorus trichloride

Phosphorus trichloride

  • Formula as often written: PCl3
  • Hill system formula: Cl3P1
  • CAS registry number: [7719-12-2]
  • Formula weight: 137.332
  • Class: chloride

Synonyms

  • phosphorus trichloride
  • phosphorus(III) chloride
  • phosphorus chloride

Physical properties

  • Colour: colourless
  • Appearance: liquid
  • Melting point: -112°C
  • Boiling point: 76°C
  • Density: 1575 kg m-3

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Element analysis

Element percentages for the elements in phosphorus trichloride
Element %
Cl 77.45
P 22.55

Synthesis

Not available

Solid state structure

  • Geometry of phosphorus: 3 coordinate: pyramidal
  • Prototypical structure:

Crystal structure of phosphorus trichloride

Isotope pattern

What follows is the calculated isotope pattern for the PCl3 unit with the most intense ion set to 100%.

Formula: P1Cl3

mass  %
136 100.0 __________________________________________________
137 0.0
138 95.9 ________________________________________________
139 0.0
140 30.7 _______________
141 0.0
142 3.3 __

References

The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

  • R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
  • N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
  • F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
  • A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
  • R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
  • A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
  • A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
  • J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
  • D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
  • J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
  • J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.

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