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Osmium compounds: heptaosmium uneicosacarbonyl
The osmium in heptaosmium uneicosacarbonyl formally is in the oxidation state 0.
Heptaosmium uneicosacarbonyl
- Formula as often written: Os7(CO)21
- Hill system formula: C21O21Os7
- CAS registry number: [59158-84-8]
- Formula weight: 1919.822
- Class: carbonyl
complex
organometallic
Synonyms
- heptaosmium uneicosacarbonyl
- osmium(O) carbonyl
- aosmium uneicosacarbonyl
- heptaaosmium 21 carbonyl
- osmium carbonyl
Physical properties
- Colour: orange-brown
- Appearance: crystalline solid
- Melting point:
- Boiling point:
- Density:
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Element analysis
Element percentages for the elements in heptaosmium uneicosacarbonyl
| Element |
% |
| C |
13.14 |
| O |
17.50 |
| Os |
69.36 |
Synthesis
Not available
Isotope pattern
What follows is the calculated isotope pattern for the Os7(CO)21 unit with the most intense ion set to 100%.
Formula: Os7C21O21
mass %
1903 0.1 1904 0.1 1905 0.3 1906 0.5 1907 1.2 _ 1908 2.3 _ 1909 4.1 __ 1910 7.1 ____ 1911 11.4 ______ 1912 17.6 _________ 1913 25.6 _____________ 1914 35.9 __________________ 1915 47.5 ________________________ 1916 60.8 ______________________________ 1917 73.0 ____________________________________ 1918 85.6 ___________________________________________ 1919 93.1 _______________________________________________ 1920 100.0 __________________________________________________ 1921 97.9 _________________________________________________ 1922 96.7 ________________________________________________ 1923 83.8 __________________________________________ 1924 76.8 ______________________________________ 1925 57.1 _____________________________ 1926 49.3 _________________________ 1927 29.8 _______________ 1928 25.2 _____________ 1929 10.6 _____ 1930 10.0 _____ 1931 2.4 _ 1932 2.2 _ 1933 0.5 1934 0.2
References
The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.
- R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
- N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
- F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
- A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
- R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
- A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
- A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
- J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
- D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
- J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
- J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.
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