Iridium compounds: tetrairidium dodecacarbonyl

iridium symbol icon

The iridium in tetrairidium dodecacarbonyl formally is in the oxidation state 0.

Crystal structure of tetrairidium dodecacarbonyl

Tetrairidium dodecacarbonyl

  • Formula as often written: Ir4(CO)12
  • Hill system formula: C12Ir4O12
  • CAS registry number: [18827-81-1]
  • Formula weight: 1104.989
  • Class: carbonyl complex organometallic

Synonyms

  • tetrairidium dodecacarbonyl
  • iridium(O) carbonyl
  • iridium carbonyl
  • iridium dodecacarbonyl

Physical properties

  • Colour: yellow
  • Appearance: crystalline solid
  • Melting point: 195°C (decomposes)
  • Boiling point:
  • Density:

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Element analysis

Element percentages for the elements in tetrairidium dodecacarbonyl
Element %
C 13.04
Ir 69.58
O 17.38

Synthesis

Not available

Solid state structure

  • Geometry of iridium:
  • Prototypical structure:

Crystal structure of tetrairidium dodecacarbonyl

Isotope pattern

What follows is the calculated isotope pattern for the Ir4(CO)12 unit with the most intense ion set to 100%.

Formula: Ir4C12O12

mass  %
1100   5.1 ___
1101 0.7
1102 34.5 _________________
1103 4.8 __
1104 87.8 ____________________________________________
1105 12.1 ______
1106 100.0 __________________________________________________
1107 13.8 _______
1108 44.1 ______________________
1109 6.0 ___
1110 1.4 _
1111 0.2
1112 0.0

References

The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

  • R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
  • N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
  • F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
  • A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
  • R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
  • A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
  • A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
  • J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
  • D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
  • J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
  • J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.

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iridium atomic number