Beryllium compounds: beryllium dibromide

beryllium symbol icon

The beryllium in beryllium dibromide formally is in the oxidation state 2.

Beryllium dibromide

  • Formula as often written: BeBr2
  • Hill system formula: Be1Br2
  • CAS registry number: [7787-46-4]
  • Formula weight: 168.82
  • Class: bromide

Synonyms

  • beryllium dibromide
  • beryllium(II) bromide
  • beryllium bromide

Physical properties

  • Colour: white
  • Appearance: crystalline solid
  • Melting point: 508°C
  • Boiling point: 520°C; 490°C
  • Density: 3465 kg m-3

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Element analysis

Element percentages for the elements in beryllium dibromide
Element %
Be 5.34
Br 94.66

Synthesis

Beryllium bromide can be made by the direct reaction of the elements at warm temperatures. This involves carrying the bromine over the beryllium in a stream of argon gas.

Be(s) + Br2(g) (50°C) → BeBr2(s)

Isotope pattern

What follows is the calculated isotope pattern for the BeBr2 unit with the most intense ion set to 100%.

Formula: Be1Br2

mass  %
167  51.4 __________________________
168 0.0
169 100.0 __________________________________________________
170 0.0
171 48.6 ________________________

References

The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

  • R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
  • N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
  • F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
  • A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
  • R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
  • A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
  • A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
  • J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
  • D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
  • J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
  • J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.

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beryllium atomic number